2-carboethoxy-6-dimethylaminofulvene | 61857-27-0

• 英文名称: 2-carboethoxy-6-dimethylaminofulvene
• 英文别名: 2-Ethoxycarbonyl-6-dimethylamino-fulven；1-(ethoxycarbonyl)-6-(dimethylamino)pentafulvene
• CAS: 61857-27-0
• 化学式: C₁₁H₁₅NO₂
• 分子量: 193.246
• InChiKey: KDACFRIVYRAEBK-UHFFFAOYSA-N

物化性质

• 熔点：
  92 °C
• 沸点：
  283.7±33.0 °C(Predicted)
• 密度：
  1.147±0.06 g/cm3(Predicted)

反应信息

• 作为反应物：
  描述：

  2-carboethoxy-6-dimethylaminofulvene 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 4.0h， 以90%的产率得到2-carboethoxy-6-hydroxyfulvene
  参考文献：
  名称：

  The synthesis and characterization of 1-formyl-2-acylcyclopentadienylthallium compounds

  摘要：

  The reaction of sodium cyclopentadienide with RCOOEt (R = Me, Ph, 2-thienyl, or OEt) or Bu'COCl followed by Vilsmeier reagent in the presence of excess sodium methoxide produces the 2-substituted-6-dimethylaminofulvenes la-C in modest yields. Basic hydrolysis results in the formation of 2-substituted-6-hydroxyfulvenes 2a-e in very good yields, Subsequent deprotonation with TlOEt yields the 1-formyl-2-acyl or carboethoxy cyclopentadienylthallium compounds 3a-e. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01185-8
• 作为产物：
  描述：

  N,N-二甲基甲酰胺 、 Cyclopenta-2,4-dienecarboxylic acid ethyl ester 在 sodium methylate 、 三氯氧磷 作用下， 反应 4.0h， 生成 2-carboethoxy-6-dimethylaminofulvene
  参考文献：
  名称：

  The synthesis and characterization of 1-formyl-2-acylcyclopentadienylthallium compounds

  摘要：

  The reaction of sodium cyclopentadienide with RCOOEt (R = Me, Ph, 2-thienyl, or OEt) or Bu'COCl followed by Vilsmeier reagent in the presence of excess sodium methoxide produces the 2-substituted-6-dimethylaminofulvenes la-C in modest yields. Basic hydrolysis results in the formation of 2-substituted-6-hydroxyfulvenes 2a-e in very good yields, Subsequent deprotonation with TlOEt yields the 1-formyl-2-acyl or carboethoxy cyclopentadienylthallium compounds 3a-e. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01185-8

文献信息

• Rhodium and iridium complexes of a new ferrocene-derived chelating bis(NHC) ligand
  作者：Dmitriy M. Panov、Pavel V. Petrovskii、Mariam G. Ezernitskaya、Alexander F. Smol'yakov、Fedor M. Dolgushin、Avthandil A. Koridze

  DOI：10.1039/c2dt30898c

  日期：——

  Rhodium and iridium complexes of a new ferrocene-derived bis(N-heterocyclic carbene) ligand, [M(cod)1,2-(MeNCHCHNCCH2)2C5H3}Fe(C5H5)]BF4 (M = Rh, 8a; M = Ir, 8b; cod = 1,5-cyclooctadiene), were synthesized from the corresponding bis(imidazolium) salt 6. The molecular structure of 8a was determined by single-crystal X-ray diffraction. Complexes 8a and 8b smoothly react with CO with displacement of

  新的二茂铁衍生的双（N-杂环卡宾）配体[M（cod）1,2-（MeNCHCHNCCH 2）2 C 5 H 3 } Fe（C 5 H 5）] BF 4（ M = Rh，8a； M = Ir，8b； cod =1,5-环辛二烯），是由相应的双（咪唑）盐6合成。通过单晶X射线衍射确定8a的分子结构。配合物8a和8b与CO平稳地反应，置换了螯合的鳕鱼配体，得到了相应的二羰基衍生物9a和9b。
• Bickert, Peter; Hildebrandt, Bernhard; Hafner, Klaus, Organometallics, 1984, vol. 3, # 5, p. 653 - 663
  作者：Bickert, Peter、Hildebrandt, Bernhard、Hafner, Klaus

  DOI：——

  日期：——