[AuTl(C6Cl5)2(ethylenediamine)] | 882878-54-8

• 英文名称: [AuTl(C6Cl5)2(ethylenediamine)]
• 英文别名: [AuTl(C6Cl5)2(en)]
• CAS: 882878-54-8
• 化学式: C₁₄H₈AuCl₁₀N₂Tl
• 分子量: 960.11
• InChiKey: MWRVUHDYFPGXDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [AuTl(C6Cl5)2(ethylenediamine)] 、 丙酮 以 四氢呋喃 为溶剂， 以75%的产率得到[AuTl(C6Cl5)2(NH2CH2CH2NC(CH3)2]n
  参考文献：
  名称：

  Easy Ketimine Formation Assisted by Heteropolynuclear Gold−Thallium Complexes

  摘要：

  Treatment of the heterometallic complexes [AuTl(C6X5)(2)(L-1)] (X = Cl (1a), F (1b), L-1 = ethylenediamine) with ketones at room temperature yields stable amine-imine or diimine complexes with the new ligands bound to the thallium centers. Besides their reactivity in solution, both amine complexes 1a and 1b react in the solid state with ketone vapors at room temperature in a few seconds.

  DOI：

  10.1021/om051030j
• 作为产物：
  描述：

  [AuTl(C6Cl5)2(PhMeC=N(CH2)2N=CMePh)]n 、 乙二胺 以 not given 为溶剂， 以99%的产率得到[AuTl(C6Cl5)2(ethylenediamine)]
  参考文献：
  名称：

  Easy Ketimine Formation Assisted by Heteropolynuclear Gold−Thallium Complexes

  摘要：

  Treatment of the heterometallic complexes [AuTl(C6X5)(2)(L-1)] (X = Cl (1a), F (1b), L-1 = ethylenediamine) with ketones at room temperature yields stable amine-imine or diimine complexes with the new ligands bound to the thallium centers. Besides their reactivity in solution, both amine complexes 1a and 1b react in the solid state with ketone vapors at room temperature in a few seconds.

  DOI：

  10.1021/om051030j