6-diphenylphosphinyl-2,5-dimethyl-1,3,4-triethyl-2,3,4,5-tetracarba-nido-hexaborane(6) | 215920-87-9

• 英文名称: 6-diphenylphosphinyl-2,5-dimethyl-1,3,4-triethyl-2,3,4,5-tetracarba-nido-hexaborane(6)
• CAS: 215920-87-9
• 化学式: C₂₄H₃₁B₂P
• 分子量: 372.106
• InChiKey: CCAYHYZHRUQCLM-KEZOAJOQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (2R,3R,5R,6S)-1,4,5-triethyl-2-iodo-3,6-dimethyl-1l6,2l4-diborapentacyclo[2.2.0.01,3.01,5.02,6]hexane 、 6-diphenylphosphinyl-2,5-dimethyl-1,3,4-triethyl-2,3,4,5-tetracarba-nido-hexaborane(6) 、 tungsten pentacarbonyl tetrahydrofuran 以 四氢呋喃 为溶剂， 生成 、
  参考文献：
  名称：

  PENTAALKYL-6-DIPHENYLPHOSPHINO-2,3,4,5-TETRACARBA-NIDO-HEXABORANES(6)

  摘要：

  Pentaalkyl-6-bromo-2,3,4,5-tetracarba-nido-hexaboranes(6) (3-carb-Br and 4-carb-Br) react with lithium-diphenylphosphide to give the 6-diphenylphosphino substituted carboranes 3-carb-PPh2 and 4-carb-PPh2, 3-carb-PPh2 can be oxidized to give the respective oxide, sulfide and selenide. Treatment of 4-carb-PPh2 with an excess of methyl iodide cleaves the P-B bond and 4-carb-I is formed together with [Me2Ph2P]I+. 4-carb-PPh2 reacts with borane in tetrahydrofuran (BH3-THF/THF) or W(CO)(5)-THF/THF to give the BH3 and W(CO)(5) complexes. AU products were characterized by H-1, B-11, C-13 and P-31 NMR spectroscopy.

  DOI：

  10.1080/10426509708031593
• 作为产物：
  描述：

  6-bromo-2,5-dimethyl-1,3,4-triethyl-2,3,4,5-tetracarba-nido-hexaborane⁽⁶⁾ 、 6-bromo-2,4-dimethyl-1,3,5-triethyl-2,3,4,5-tetracarba-nido-hexaborane⁽⁶⁾ 、 二苯基膦酸锂 以 正己烷 为溶剂， 生成 6-diphenylphosphinyl-2,5-dimethyl-1,3,4-triethyl-2,3,4,5-tetracarba-nido-hexaborane(6) 、 6-diphenylphosphinyl-2,4-dimethyl-1,3,5-triethyl-2,3,4,5-tetracarba-nido-hexaborane(6)
  参考文献：
  名称：

  PENTAALKYL-6-DIPHENYLPHOSPHINO-2,3,4,5-TETRACARBA-NIDO-HEXABORANES(6)

  摘要：

  Pentaalkyl-6-bromo-2,3,4,5-tetracarba-nido-hexaboranes(6) (3-carb-Br and 4-carb-Br) react with lithium-diphenylphosphide to give the 6-diphenylphosphino substituted carboranes 3-carb-PPh2 and 4-carb-PPh2, 3-carb-PPh2 can be oxidized to give the respective oxide, sulfide and selenide. Treatment of 4-carb-PPh2 with an excess of methyl iodide cleaves the P-B bond and 4-carb-I is formed together with [Me2Ph2P]I+. 4-carb-PPh2 reacts with borane in tetrahydrofuran (BH3-THF/THF) or W(CO)(5)-THF/THF to give the BH3 and W(CO)(5) complexes. AU products were characterized by H-1, B-11, C-13 and P-31 NMR spectroscopy.

  DOI：

  10.1080/10426509708031593