4-PyCH2OCS2Re(bipy)(CO)3 | 1217190-71-0

• 英文名称: 4-PyCH2OCS2Re(bipy)(CO)3
• CAS: 1217190-71-0
• 化学式: C₂₀H₁₄N₃O₄ReS₂
• 分子量: 610.688
• InChiKey: CZAMUVNODZWWQI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  4-PyCH2OCS2Re(bipy)(CO)3 、 以 二氯甲烷 为溶剂， 以78.3%的产率得到[(CH3OCH2CH2OP(anisole)S2)2Ni][4-PyCH2OCS2Re(2,2'-bipyridine)(CO)3]2
  参考文献：
  名称：

  Functionalized O-Alkyldithiocarbonates: A New Class of Ligands Designed for Luminescent Heterometallic Materials

  摘要：

  The new ligand 4-PyCH(2)OCS(2)Na, that combines two different donor groups in one molecule (a soft -CS(2)(-) group and a hard pyridine moiety), has been synthesized. The ligand coordinates to a [(bipy)Re(CO)(3)](+) center in a monodentate fashion through one of its soft sulfur atoms, leaving the hard pyridine terminus free for further coordination chemistry. Using a Ni(II) dithiophosphonate linker, the heterometallic {[CH(3)OCH(2)CH(2)OP(An)S(2)](2)Ni}[4-PyCH(2)OCS(2)Re(bipy)-(CO)(3)](2) Complex is obtained, through the coordination of two pyridine groups to the Ni(II) center. This simple, high-yield stepwise strategy toward heterometallic complexes could be easily transferable to other 1, 1-dithiolate ligands and used in combination with a large variety of luminescent metallic systems.

  DOI：

  10.1021/ic901551t
• 作为产物：
  描述：

  [Re(CO)3(bipy)(CH3CN)][CF3SO3] 、 4-PyCH2OCS2Na 以 丙酮 为溶剂， 以82.1%的产率得到4-PyCH2OCS2Re(bipy)(CO)3
  参考文献：
  名称：

  Functionalized O-Alkyldithiocarbonates: A New Class of Ligands Designed for Luminescent Heterometallic Materials

  摘要：

  The new ligand 4-PyCH(2)OCS(2)Na, that combines two different donor groups in one molecule (a soft -CS(2)(-) group and a hard pyridine moiety), has been synthesized. The ligand coordinates to a [(bipy)Re(CO)(3)](+) center in a monodentate fashion through one of its soft sulfur atoms, leaving the hard pyridine terminus free for further coordination chemistry. Using a Ni(II) dithiophosphonate linker, the heterometallic {[CH(3)OCH(2)CH(2)OP(An)S(2)](2)Ni}[4-PyCH(2)OCS(2)Re(bipy)-(CO)(3)](2) Complex is obtained, through the coordination of two pyridine groups to the Ni(II) center. This simple, high-yield stepwise strategy toward heterometallic complexes could be easily transferable to other 1, 1-dithiolate ligands and used in combination with a large variety of luminescent metallic systems.

  DOI：

  10.1021/ic901551t