1,2-(1,1'-ferrocenediyl)ethene | 186376-49-8

• 英文名称: 1,2-(1,1'-ferrocenediyl)ethene
• 英文别名: ansa-(vinylene)ferrocene
• CAS: 186376-49-8
• 化学式: C₁₂H₁₀Fe
• 分子量: 210.058
• InChiKey: SYWKJJGCXIALNB-KVVVOXFISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,2-(1,1'-ferrocenediyl)ethene 、 苯甲醛 在 Mo ROMP 作用下， 以 苯 为溶剂， 以94%的产率得到[poly(norbornylene)]-block-[poly(ferrocenylenevinylene)]
  参考文献：
  名称：

  Poly(ferrocenylenevinylene) from Ring-Opening Metathesis Polymerization of ansa-(Vinylene)ferrocene

  摘要：

  The vinylene-bridged ansa-ferrocene complex [(eta(5)-C5H4)CH=CH(eta(5)-C5H4)]Fe (1) was synthesized by the McMurry coupling of 1,1'-ferrocenedicarbaldehyde (2). The ring opening metathesis polymerization (ROMP) of this strained metallocene gave poly(ferrocenylenevinylene) (3) as an insoluble orange solid which has a conductivity of 10(-3) Omega(-1) cm(-1) after doping with iodine. Partially soluble materials resulted when 1 was copolymerized with norbornene to yield a block copolymer.

  DOI：

  10.1021/om960940l
• 作为产物：
  描述：

  1,1'-二茂铁二甲醛 在 TiCl₃ 、 Zn/Cu 作用下， 以 乙二醇二甲醚 为溶剂， 以44%的产率得到1,2-(1,1'-ferrocenediyl)ethene
  参考文献：
  名称：

  Poly(ferrocenylenevinylene) from Ring-Opening Metathesis Polymerization of ansa-(Vinylene)ferrocene

  摘要：

  The vinylene-bridged ansa-ferrocene complex [(eta(5)-C5H4)CH=CH(eta(5)-C5H4)]Fe (1) was synthesized by the McMurry coupling of 1,1'-ferrocenedicarbaldehyde (2). The ring opening metathesis polymerization (ROMP) of this strained metallocene gave poly(ferrocenylenevinylene) (3) as an insoluble orange solid which has a conductivity of 10(-3) Omega(-1) cm(-1) after doping with iodine. Partially soluble materials resulted when 1 was copolymerized with norbornene to yield a block copolymer.

  DOI：

  10.1021/om960940l

文献信息

• First synthesis and X-ray crystal structure of 1,2-(1,1′-ferrocenediyl)ethene
  作者：Varinder K. Aggarwal、David Jones、Michael L. Turner、Harry Adams

  DOI：10.1016/s0022-328x(96)06330-9

  日期：1996.11

  The ethene-bridged ferrocenophane, 1,2-(1,1'-ferrocenediyl)ethene, has been prepared in six steps from ferrocene using a Stevens rearrangement as the key step to construct the strained bridge.