10-(3,5-bis(decyloxy)phenyl)-2,8-bis((4-(tert-butyl)phenyl)ethynyl)-5,5-difluoro-1,3,7,9-tetramethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium | 1191301-55-9

• 英文名称: 10-(3,5-bis(decyloxy)phenyl)-2,8-bis((4-(tert-butyl)phenyl)ethynyl)-5,5-difluoro-1,3,7,9-tetramethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
• CAS: 1191301-55-9
• 化学式: C₆₃H₈₃BF₂N₂O₂
• 分子量: 949.172
• InChiKey: BLIUHLVJGMYUAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  10-(3,5-bis(decyloxy)phenyl)-2,8-bis((4-(tert-butyl)phenyl)ethynyl)-5,5-difluoro-1,3,7,9-tetramethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium 、 4-(丙-2-炔-1-基氧基)苯甲醛 在 哌啶 、 溶剂黄146 作用下， 以 苯 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Tetrastyryl-BODIPY-Based Dendritic Light Harvester and Estimation of Energy Transfer Efficiency

  摘要：

  Versatile BODIPY dyes can be transformed into bright near-IR-emitting fluorophores by quadruple styryl substitutions. When clickable functionalities on the styryl moieties are inserted, an efficient synthesis of a light harvester is possible. In addition, clear spectral evidence is presented showing that, in dendritic light harvesters, calculations commonly based on quantum yield or emission lifetime changes of the donor are bound to yield large overestimations of energy transfer efficiency.

  DOI：

  10.1021/ol301462x
• 作为产物：
  描述：

  4,4-difluoro-8-[3',5'-bis(decyloxy)phenyl]-2,6-diiodo-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene 、 4-叔-丁基苯基乙炔 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 二异丙胺 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以80%的产率得到10-(3,5-bis(decyloxy)phenyl)-2,8-bis((4-(tert-butyl)phenyl)ethynyl)-5,5-difluoro-1,3,7,9-tetramethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
  参考文献：
  名称：

  Tetrastyryl-Bodipy Dyes: Convenient Synthesis and Characterization of Elusive Near IR Fluorophores

  摘要：

  1,3,5,7-Tetramethyl-Bodipy derivatives undergo Knoevenagel-type condensations with aromatic aldehydes to ultimately yield tetrastyryl-Bodipy derivatives. The resulting dyes absorb and emit strongly in the near IR. As the versatility of the Bodipy dyes are fully appreciated, these new tetrastyryl dyes are likely to be featured in a variety of functional supramolecular systems.

  DOI：

  10.1021/ol9019056