bis(2-[(2-hydroxybenzyl)iminomethyl]phenolato(2-)-O:O,N,O')dicopper(II) | 72043-67-5

• 英文名称: bis(2-[(2-hydroxybenzyl)iminomethyl]phenolato(2-)-O:O,N,O')dicopper(II)
• CAS: 72043-67-5
• 化学式: C₂₈H₂₂Cu₂N₂O₄
• 分子量: 577.586
• InChiKey: QHPMJBBEHSXYIZ-QDXVZHPMSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-(2-hydroxybenzyl)salicylaldimine 、 copper(II) acetate monohydrate 在 piperidine 作用下， 以 甲醇 为溶剂， 生成 bis(2-[(2-hydroxybenzyl)iminomethyl]phenolato(2-)-O:O,N,O')dicopper(II)
  参考文献：
  名称：

  Bis{2-[(2-hydroxybenzyl)iminomethyl]phenolato(2 –)-O:O,N,O'}dicopper(II)

  摘要：

  The title compound, [Cu-2(C14H11NO2)(2)], consists Of doubly oxygen-bridged centrosymmetric copper dimers. Each Cu atom has a distorted square-planar environment involving three O atoms and an N atom of the ligands. The Cu-O distances in the coordination plane vary from 1.881 (8) to 1.930 (10) Angstrom and the Cu-N distance is 1.920 (10) Angstrom. In the bridging plane, the Cu-O-Cu' and O-Cu-O' angles are 103.5 (4) and 76.5 (3)degrees,respectively. The Cu ... Cu' distance is 3.073 (2) Angstrom.

  DOI：

  10.1107/s0108270196012590