| 201293-14-3

• CAS: 201293-14-3
• 化学式: C₃₄H₂₉FeP₂Pt
• 分子量: 750.479
• InChiKey: CLOGMDKBUFWBPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,1'-双(二苯基膦)二茂铁 、 以 四氢呋喃 为溶剂， 生成 [Pt(1,1′-bis(diphenylphosphanyl)ferrocene)₂]
  参考文献：
  名称：

  Synthesis and Structure of a Cationic Diplatinum μ-Alkylidene μ-Hydride Complex

  摘要：

  The dinuclear mu-alkylidene mu-hydride cation [Pt-2(dppf)(2)(mu-CHCH2Ar)(mu-H)][Br] (2, dppf = Ph2PC5H4FeC5H4PPh2, Ar = p-MeOC6H4) was obtained unexpectedly from reaction of p-methoxybromostyrene (3) with Pt(dppf)Cl-2/NaBH4/norbornene and crystallographically characterized. Solutions of the hydride [Pt(dppf)H](2) (7), prepared by deprotonation of the known cation [Pt-2(dppf)(2)H-3](+) (6) or by treatment of Pt(dppf)Cl-2 with two equiv of LiBEt3H, deposit an insoluble precipitate formulated as [Pt(dppf)H](n) (11), which also gives 2 on treatment with 3.

  DOI：

  10.1021/om9708034
• 作为产物：
  描述：

  [1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride 、 三乙基硼氢化锂 以 四氢呋喃 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Synthesis and Structure of a Cationic Diplatinum μ-Alkylidene μ-Hydride Complex

  摘要：

  The dinuclear mu-alkylidene mu-hydride cation [Pt-2(dppf)(2)(mu-CHCH2Ar)(mu-H)][Br] (2, dppf = Ph2PC5H4FeC5H4PPh2, Ar = p-MeOC6H4) was obtained unexpectedly from reaction of p-methoxybromostyrene (3) with Pt(dppf)Cl-2/NaBH4/norbornene and crystallographically characterized. Solutions of the hydride [Pt(dppf)H](2) (7), prepared by deprotonation of the known cation [Pt-2(dppf)(2)H-3](+) (6) or by treatment of Pt(dppf)Cl-2 with two equiv of LiBEt3H, deposit an insoluble precipitate formulated as [Pt(dppf)H](n) (11), which also gives 2 on treatment with 3.

  DOI：

  10.1021/om9708034