[(η6-mesitylene)Fe(Me2SiC6H4SiMe2)(CO)] | 1428536-27-9

• 英文名称: [(η6-mesitylene)Fe(Me2SiC6H4SiMe2)(CO)]
• 英文别名: [(η⁶-mesitylene)Fe(Me₂SiC₆H₄SiMe₂)(CO)]
• CAS: 1428536-27-9
• 化学式: C₂₀H₂₈FeOSi₂
• 分子量: 396.46
• InChiKey: VFTIMGZOEVNJFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η6-mesitylene)Fe(Me2SiC6H4SiMe2)(CO)] 、 氢气 以 均三甲苯 为溶剂， 20.0 ℃ 、101.33 kPa 条件下， 反应 30.0h， 以86%的产率得到[(η6-mesitylene)Fe(Me2SiC6H4SiMe2)(H)2]
  参考文献：
  名称：

  Disilametallacycles as a Platform for Stabilizing M(II) and M(IV) (M = Fe, Ru) Centers: Synthesis and Characterization of Half-Sandwich Complexes and Their Application to Catalytic Double Silylation of Alkenes and Alkynes

  摘要：

  A series of group 8 half-sandwich disilametallacycles, (eta(6)-arene)M-II(Me2SiC6H4SiMe2)L and (eta(6)-arene)M-IV(H)(2)(Me2SiC6H4SiMe2) (M = Fe, Ru) in the formal oxidation states of M(II) and M(IV) were synthesized and characterized. Both the M(II) and the M(IV) oxidation states were effectively stabilized by the disilametallacycle skeleton, and facile interconversion between (eta(6)-arene)M-II-dinitrogen, (eta(6)-arene)M-II-carbonyl, and (eta(6)-arene)M-IV-dihydride complexes bearing a disilaferracycle framework was accomplished. These M(II) and M(IV) complexes can easily generate coordinatively unsaturated 16e disilametallacycles, (eta(6)-arene)M-II(Me2SiC6H4SiMe2), by dissociation of L or H-2, and stoichiometric and/or catalytic double silylation of alkenes and alkynes was realized thorough this 16e intermediate.

  DOI：

  10.1021/om3012322
• 作为产物：
  描述：

  一氧化碳 、 [(η⁶-mesitylene)Fe(Me₂SiC₆H₄SiMe₂)]₂(µ-η¹:η¹-N₂) 以 均三甲苯 为溶剂， 20.0 ℃ 、101.33 kPa 条件下， 反应 16.0h， 以94%的产率得到[(η6-mesitylene)Fe(Me2SiC6H4SiMe2)(CO)]
  参考文献：
  名称：

  Disilametallacycles as a Platform for Stabilizing M(II) and M(IV) (M = Fe, Ru) Centers: Synthesis and Characterization of Half-Sandwich Complexes and Their Application to Catalytic Double Silylation of Alkenes and Alkynes

  摘要：

  A series of group 8 half-sandwich disilametallacycles, (eta(6)-arene)M-II(Me2SiC6H4SiMe2)L and (eta(6)-arene)M-IV(H)(2)(Me2SiC6H4SiMe2) (M = Fe, Ru) in the formal oxidation states of M(II) and M(IV) were synthesized and characterized. Both the M(II) and the M(IV) oxidation states were effectively stabilized by the disilametallacycle skeleton, and facile interconversion between (eta(6)-arene)M-II-dinitrogen, (eta(6)-arene)M-II-carbonyl, and (eta(6)-arene)M-IV-dihydride complexes bearing a disilaferracycle framework was accomplished. These M(II) and M(IV) complexes can easily generate coordinatively unsaturated 16e disilametallacycles, (eta(6)-arene)M-II(Me2SiC6H4SiMe2), by dissociation of L or H-2, and stoichiometric and/or catalytic double silylation of alkenes and alkynes was realized thorough this 16e intermediate.

  DOI：

  10.1021/om3012322