{Co2(mu.-C2H5SCH2CCCH2SC2H5)(CO)6} | 134097-47-5

• 英文名称: {Co2(mu.-C2H5SCH2CCCH2SC2H5)(CO)6}
• CAS: 134097-47-5
• 化学式: C₁₄H₁₄Co₂O₆S₂
• 分子量: 460.38
• InChiKey: WDLMIQZKLCXESN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  {Co2(mu.-C2H5SCH2CCCH2SC2H5)(CO)6} 、 双二苯基膦甲烷 以 苯 为溶剂， 以60%的产率得到{Co2(μ-C2H5SCH2CCCH2SC2H5)(CO)4(μ-dppm)}
  参考文献：
  名称：

  The synthesis of dimetallic thioalkyne complexes of cobalt and molybdenum

  摘要：

  Treatment of [Co2(mu-HOCR2'C=CCR2'OH)(CO)6] With an excess of RSH in the presence of HBF4.OEt2 affords [Co2(mu-RSCR2'C=CCR2'SR)(CO)6] (R'= H, R = Et, (n)Bu, (t)Bu, Ph, Bz; R'= Me, R = Et), which undergo substitution with bis(diphenylphosphino)methane (dppm) to give [Co2(mu-RSCR2'C=CCR2'SR)(mu-dppm)(CO)4]. Similar treatment of [MoCo(mu-HOCH2C=CCH2OH)(CO)5Cp] and [Mo2(mu-HOCH2C=CCH2OH)(CO)4Cp2] with EtSH gives [MoCo(mu-EtSCH2C=CCH2SEt)(CO)5-Cp] and [Mo2(mu-EtSCH2C=CCH2SEt)(CO)4Cp2], respectively. Reaction of [Co2(mu-HOCH2C=CCH2-OH)(CO)6] with a small excess of RSH (R=Et or Ph), ca. two equivalents, affords [Co2(mu-HOCH2C=CCH2-SR)(CO)6], while reaction with only one equivalent of EtSH additionally gives an ether-bridged system containing two hexacarbonyldicobalt units, [Co2(CO)6(HOCH2C= CCH2OCH2C=CCH2SEt)-Co2(CO)6]. Treatment of [Co2(mu-HOCH2C=CCH2SEt)(CO)6] with half an equivalent of HBF4.OEt2 affords [Co2(CO)6(EtSCH2C=CCH2OCH2C=CCH2SEt)Co2(CO)6]. Attempted preparation of mixed thioether complexes results in a mixture of products, and a mechanism is proposed for thioether scrambling. The IR, NMR and mass spectra of the new compounds are reported and discussed.

  DOI：

  10.1016/0022-328x(92)80229-q
• 作为产物：
  描述：

  2-butyne-1,4-diol-hexacarbonyldicobalt 、 乙硫醇 在 HBF₄ 作用下， 以 二氯甲烷 为溶剂， 生成 {Co2(mu.-C2H5SCH2CCCH2SC2H5)(CO)6}
  参考文献：
  名称：

  Formation of novel bidentate and crown thioether ligands via dicobalt alkyne complexes

  摘要：

  通过[Co2(µ-HOCH2CCCH2OH)(CO)6]与一元硫醇和二元硫醇在 HBF4 存在下的反应，制备了能够与金属羰基配位的开链和环状硫代炔烃配合物。并通过 X 射线晶体学确定了 [Co2(CO)4(µ-dppm){µ-C2(CH2SMe)2}Mo(CO)4] 和 [Co2{µ-C2(CH2SCH2CH2)2S}(CO)6] 的结构；dppm = 双（二苯基膦）甲烷。

  DOI：

  10.1039/c39910000349

文献信息

• Synthesis and reactivity of dicobalt stabilised but-2-yne-1,4-dicarbenium ions
  作者：Stephen C. Bennett、Mark A. Phipps、Michael J. Went

  DOI：10.1039/c39940000225

  日期：——

  Treatment of [Co2(µ-HOCH2CCCH2OH)(CO)6] in Me2S with HBF4·OEt2 affords the stable salt [Co2(µ-Me2SCH2CCCH2SMe2)(CO)6][BF4]2 which reacts with secondary amines to afford [Co2(µ-R2NCH2CCCH2NR2)(CO)6](R = Et or Ph), while treatment of [Co2(µ-HOCH2CCCH2OH)(µ-dppm)2(CO)2][dppm = bis(diphenylphosphino)methane] with HBF4·OEt2 affords a stable dicarbenium complex [Co2(µ-H2CCCCH2)(µ-dppm)2(CO)2][BF4]2 which forms adducts with pyridine and triphenylphosphine.

  用 HBF4-OEt2 处理 Me2S 中的 [Co2(µ-HOCH2CCCH2OH)(CO)6]，可得到稳定盐 [Co2(µ-Me2SCH2CCCH2SMe2)(CO)6][BF4]2，该盐与仲胺反应生成 [Co2(µ-R2NCH2CCCH2NR2)(CO)6]（R = Et 或 Ph）、而用 -OEt2 处理[Co2(µ-HOCH2CCCH2OH)(µ-dppm)2(CO)2][dppm = 双（二苯基膦）甲烷]会得到稳定的二钡络合物[Co2(µ-H2CCCCH2)(µ-dppm)2(CO)2][BF4]2，该络合物会与吡啶和三苯基膦形成加合物。