| 748189-35-7

• CAS: 748189-35-7
• 化学式: C₂₅H₂₇ClO₂PRu*F₆P
• 分子量: 671.949
• InChiKey: IBDYGGRUWMYLCK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三乙胺 以 丙酮 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Diastereoselective Oxidative Addition of Allyl Chloride to Planar-Chiral Cyclopentadienyl−Ruthenium Complexes

  摘要：

  The reaction of planar-chiral cyclopentadienyl-ruthenium complexes with allyl chloride at room temperature resulted in the diastereoselective formation of pi-allyl-ruthenium complexes, in which the chirality at the Ru center depended on the substituent at the 4-position of the cyclopentadienyl group. Epimerization at the Ru center of pi-allyl complexes at 90 degreesC suggested that the diastereoselectivity was under kinetic control.

  DOI：

  10.1021/om049616d
• 作为产物：
  描述：

  [Ru(η5,η1-C5H2Me2CO2(CH2)2PPh2)(CH3CN)2][PF6] 、 3-氯丙烯 以 丙酮 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Diastereoselective Oxidative Addition of Allyl Chloride to Planar-Chiral Cyclopentadienyl−Ruthenium Complexes

  摘要：

  The reaction of planar-chiral cyclopentadienyl-ruthenium complexes with allyl chloride at room temperature resulted in the diastereoselective formation of pi-allyl-ruthenium complexes, in which the chirality at the Ru center depended on the substituent at the 4-position of the cyclopentadienyl group. Epimerization at the Ru center of pi-allyl complexes at 90 degreesC suggested that the diastereoselectivity was under kinetic control.

  DOI：

  10.1021/om049616d