bis[dichloro-(η(6)-1,2,3,4-tetramethylbenzene)ruthenium] | 88946-78-5

• 英文名称: bis[dichloro-(η(6)-1,2,3,4-tetramethylbenzene)ruthenium]
• 英文别名: bis[dichloro(η(6)-1,2,3,4-tetramethylbenzene)ruthenium]；[(η(6)-1,2,3,4-Me4C6H2)RuCl2]2；[(η(6)-1,2,3,4-Me4C6H2)RuCl]2；[RuCl(η6-1,2,3,4-tetramethylbenzene)(μ-Cl)]2；bis[dichloro(η6-1,2,3,4-Me4C6H2)ruthenium(II)]；[Ru(η(6)-1,2,3,4-C6H2(CH3)4)Cl(μ-Cl)]2
• CAS: 88946-78-5
• 化学式: C₂₀H₂₈Cl₄Ru₂
• 分子量: 612.394
• InChiKey: CTJGQXRONXDMLK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis[dichloro-(η(6)-1,2,3,4-tetramethylbenzene)ruthenium] 、 Bis-(2,6-dimethoxyphenyl)-phenyl-phosphin 以 not given 为溶剂， 以65%的产率得到(η(6)-1,2,3,4-tetramethylbenzene)RuCl[PPh(2-O-C6H3-6-OMe)(C6H3(OMe)2-2,6)]
  参考文献：
  名称：

  Arene ruthenium(II) complexes coordinated by phosphino and two phenoxide groups in tris(2,6-dimethoxyphenyl)phosphine: crystal structure of (η6-1,2,3,4-Me4C6H2)Ru[P[lcub]2,6-(MeO)2C6H3[rcub] [lcub]2-O-6-MeOC6H3[rcub;]2]

  摘要：

  The title compound has been prepared from bis[dichloro(eta(6)-arene)ruthenium] (eta(6)-arene = 1,2,3,4-C(6)Me(4)H(2) (1a), p-cymene (1b) and tris(2,6-dimethoxyphenyl)phospine (TDMPP). The crystal structure features a type of eta(3)-phosphino-two phenoxides coordination. Reactions with its related phosphines, bis(2,6-dimethoxyphenyl)phenylphosphine (BDMPP) and (2,6-dimethoxyphenyl)diphenylphosphine (MDMPP) gave complexes with eta(2)-phosphino-phenoxide and eta(1)-phosphino coordinations, and trans-RuCl2(MDMPP)(2), depending on phosphines and arene groups.

  DOI：

  10.1016/0022-328x(94)05334-8
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 四甲基萘 以 neat (no solvent) 为溶剂， 以94%的产率得到bis[dichloro-(η(6)-1,2,3,4-tetramethylbenzene)ruthenium]
  参考文献：
  名称：

  Hull Jr., John W.; Gladfelter, Wayne L., Organometallics, 1984, vol. 3, # 4, p. 605 - 613

  摘要：

  DOI：

文献信息

• Preparations and structures of (η6-arene)ruthenium(II) complexes bearing 1,1′-bis(diphenylphosphinomethyl)ferrocene or 1,1′-bis(diphenylphosphino)ferrocene
  作者：Jian-Fang Mai、Yasuhiro Yamamoto

  DOI：10.1016/s0022-328x(98)00499-9

  日期：1998.6

  [(η6-arene)RuCl]2(μ-dpmf)(PF6)23a without containing XylNC. Reactions of 1 with 1,1′-bis(diphenylphosphino)ferrocene (dppf) formed the bridged complexes [(arene)RuCl2]2(μ-dppf)] 4, as well as the dpmf complexes. The similar reactions in the presence of NaPF6 gave the chelated complexes [(η6-arene)RuCl(dppf-P,P′)](PF6) 5. Crystal structures of 2a, 2d·2CH2Cl2, 4a·CH2Cl2 and 5b were confirmed by X-ray analyses

  双反应[二氯（η 6 -arene）钌] 1用1,1'-双[（二苯基膦基）甲基]二茂铁（DPMF）得到dPMf- P，P'桥接的配合物[（η 6 -arene）的RuCl 2 ] 2（μ- dPMf）2，其中芳烃＝（a）1,2,3,4-Me 4 C 6 H 2；（b）C 6 Me 6 ; （c）对伞花烃；（d）1,2,3,5-Me 4 C 6 H 2；（e）1,3,5-Me 3 C 6 H 3；（f）1,2,3-Me 3 C 6 H 3。的治疗2与的NaPF存在二甲苯基胩（XylNC）6产生的F-配位的络合物[（η 6 -arene）的RuCl] 2（μ -dPMf）（PF 6）2图3a不含有XylNC。的反应1与形成在桥接配合物[（芳烃）的RuCl 1,1'-双（二苯基膦基）二茂铁（DPPF）2 ] 2（μ -DPPF）] 4，以及dPMf复合体。在的NaPF的存在下，类似的反应6得到螯合配合物[（η
• Preparation and characterization of ruthenium(II), rhodium(III) and iridium(III) complexes of isocyanide bearing the azo group
  作者：Yasuhiro Yamamoto、Hideki Nakamura、Jian-Fang Ma

  DOI：10.1016/s0022-328x(01)01189-5

  日期：2001.12

  (7), confirmed by X-ray analysis. Complex 8b reacted with Ag(CF3SO3), giving a rectangular tetranuclear complex 11b, [(η6-1,3,5-Me3C6H3)Ru(μ-Cl}4(μ-CNC6H4NNC6H4NC)2](CF3SO3)4 bridged by four Cl atoms and two μ-diisocyanoazobenzene ligands. Photochemical reactions of the ruthenium complexes (4 and 8) led to the decomposition of the complexes, whereas those of 5, 7, 9 and 10 underwent a trans-to-cis

  的[（η反应6 -arene）的RuCl 2 ] 2（1）（η 6 -arene = p -cymene（1A），1,3,5--ME 3 Ç 6 ħ 3（1B），1,2,3- -Me 3 C 6 H 3（1c）1,2,3,4-Me 4 C 6 H 2（1d），1,2,3,5-Me 4 C 6 H 2（1e）和C 6 Me 6（1f））或[Cp * MCl2 ] 2（M = Rh（2），Ir（3）; Cp * = C 5 Me 5）与4-异氰基偶氮苯（RNC）和4,4'-二异氰基偶氮苯（CN–R–NC）得到单核和双核络合物[（η 6 -arene）的Ru（CNC 6 ħ 4 NNC 6 ħ 5）氯2 ]（4A - ˚F）的[Cp * M（CNC 6 ħ 4 NNC 6 ħ 5）氯2 ]（5：M = RH; 6：M = Ir）的， [（η 6 -arene）的RuCl2 } 2 μ-CNC
• Dimeric complexes of ruthenium(II) and rhodium(III) bridged by 1,1′-bis( diphenylphosphinomethyl) ferrocene
  作者：Jian-Fang Ma、Yasuhiro Yamamoto

  DOI：10.1016/s0022-328x(97)00415-4

  日期：1997.1

  Reactions of bis[dichloro(arene)ruthenium] or bis[dichloro(pentamethylcyclopentadicnyl)rhodium] with 1,1′-bis[(diphenylphosphino)methyl]ferrocene (dpmf) gave the dpmf-P,P′ bridged complexes. The reactions of the arene ruthenium complexes with 1,1′-bis[diphcnylphosphino]ferrocene (dppf) formed the bridged and chelated complexes. The structures of complexes were confirmed by X-ray analysis. The cyclic

  双[二氯（亚芳基）钌]或双[二氯（五甲基环戊二烯基）铑]与1,1'-双[（二苯基膦基）甲基]二茂铁（dpmf）的反应得到了dpmf- P，P '桥联的配合物。芳烃钌配合物与1，1'-双[二苯基膦基]二茂铁（dppf）的反应形成桥连和螯合的配合物。配合物的结构通过X射线分析确认。测量了钌配合物的循环伏安法。
• Yamamoto, Yasuhiro; Sato, Ryoichi; Matsuo, Fumiko, Inorganic Chemistry, 1996, vol. 35, # 8, p. 2329 - 2336
  作者：Yamamoto, Yasuhiro、Sato, Ryoichi、Matsuo, Fumiko、Sudoh, Chihiro、Igoshi, Toshiaki

  DOI：——

  日期：——
• Preparation and characterization of pentamethylcyclopentadienylrhodium(III) and iridium(III), and (arene)ruthenium(II) complexes of 1,8-bis(diphenylphosphinomethyl)naphthalene
  作者：Yasuhiro Yamamoto、Fumio Miyauchi

  DOI：10.1016/s0020-1693(02)00797-1

  日期：2002.5

  1,8-Bis(diphenylphosphinomethyl)naphthalene (1,8-dpmn) reacted with [(arene)RuCl2](2) (1) or [Cp*MCl2](2) (2: M = Rh; 3: M = Ir) to generate the corresponding diphosphine-bridged complexes, [(arene)RuCl2}(2)(1,8-dpmp-P,P')] (4) (arene = p-cymene (a), 1,2,3-Me3C6H3 (b), 1,2,3,4-Me4C6H2 (d), 1,2,3,5-Me4C6H2 (d), C6Me6 (e)) or [(Cp*MCl2)(2)(1,8-dpmp-P,P')] (5: M=Rh; 6: M=Ir). Homonuclear complexes [(p-cymene)RuCl2}(1,8-dpmp-P,P')(arene)RuCl2}] 7ab and 7ad bearing different arene groups were prepared by the reactions of 1a with 1b (or 1d). They existed as two isomers in solution. Reactions of 2 with I or 3 gave heteronuclear complexes [(Cp*RhCl2)(1,8-dpmp-P,P') (arene)RuCl2}] (8) and [(Cp*RhCl2)(1,8-dpmp-P,P')(Cp*IrCl2)] (10). The heteronuclear complexes of iridium-ruthenium 9 were generated from 1 to 2. Complexes 1, 2 and 3 reacted with 1,8-dpmp in the presence of AgOTf to give the cationic complexes, [(arene)RuCl(1,8-dpmp-P,P')](OTf) (11) or [Cp*MCl(1,8-dpmp-P,P')](OTf) (12: M = Rh; 13: M = Ir) that showed the presence of isomers in solution. They were treated with Ag(OTf) to afford the Cl-bridged complexes, [(p-cymene)Ru(mu-Cl)}(2)(1,8-dpmp-P,P')](OTf)(2) (15a) or [Cp*M(mu-Cl)}(2)(1,8-dpmp-P,P')](OTf)(2) (16: M=Rh; 17: M = Ir). Complexes 16 and 17 cleaved the Cl-bridges with xylyl or mesityl isocyanide to generate the dimeric isocyanide complexes ;[Cp*MCl(RNC)}(2)(1,8-dpmp-P,P')](OTf)(2) (18: M=Rh; 19: M=Ir). X-ray analyses of 5, 8b, 10, 11a, 12, 15a and 18b were performed. (C) 2002 Elsevier Science B.V. All rights reserved.