mercury hydride | 13966-62-6

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• 英文名称: mercury hydride
• 英文别名: Mercury(I) hydride；mercury monohydride
• CAS: 13966-62-6
• 化学式: HHg
• 分子量: 201.598
• InChiKey: DJSHOLCMNYJYSS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.27
• 重原子数：
  1
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  汞 在 氢气 作用下， 以 gas 为溶剂， 生成 mercury hydride
  参考文献：
  名称：

  Mercury 6 ³P_Jrelaxation and intramultiplet mixing under collisions with molecular hydrogen

  摘要：

  Absolute rate constants for quenching and intramultiplet mixing of Hg(6 3P0,1,2) by collisions with H2 molecules have been determined. Some of these results are original. The other ones are compared with previous determinations. In this study the 6 3P0,1,2 levels of mercury were populated directly via pulsed laser excitation and the time evolutions of the populations were analyzed by time-resolved laser induced fluorescence.

  DOI：

  10.1063/1.455147

文献信息

• Matrix Isolated HgCH₃ Radical:  An ESR Investigation
  作者：Emmanuel Karakyriakos、Allan J. McKinley

  DOI：10.1021/jp0400925

  日期：2004.5.1

  formed in a microwave discharge and isolated in an inert neon matrix. Their electronic structure was established for the first time using electron spin resonance (ESR) spectroscopy. The following magnetic parameters were determined from the experimental spectra, g⊥ = 1.84525(20), A⊥(199Hg) = 4337(3) MHz, A⊥(201Hg) = 1604(1) MHz, A⊥(13C) = 146(2) MHz, A⊥(H) = 31(1) MHz, and A⊥(D) = 5(1) MHz. Estimates

  Hg12CH3、Hg13CH3、Hg12CD3、199Hg12CH3、201Hg12CH3、201Hg13CH3、199Hg12CD3 和 201Hg12CD3 自由基均在微波放电中形成并在惰性氖基质中分离。首次使用电子自旋共振 (ESR) 光谱确定了它们的电子结构。以下磁参数由实验光谱确定，g⊥ = 1.84525(20), A⊥(199Hg) = 4337(3) MHz, A⊥(201Hg) = 1604(1) MHz, A⊥(13C) = 146 (2) MHz，A⊥(H) = 31(1) MHz，A⊥(D) = 5(1) MHz。对以下磁参数进行了估算，g∥ = 1.990(5)，A∥(199Hg) = 5658(10) MHz，A∥(201Hg) = 2094(10) MHz，A∥(13C) = 270( 25) 兆赫。自由原子比较法 (FACM) 用于确定自由基的不成对电子自旋密度分布并建立键合模型。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Hg: MVol.B1, 1, page 1 - 13
  作者：

  DOI：——

  日期：——
• Beutler, h.; Rabinowitsch, E., Zeitschrift fur Elektrochemie, 1929, vol. 35, p. 623 - 625
  作者：Beutler, h.、Rabinowitsch, E.

  DOI：——

  日期：——
• Compton, K. T.; Turner, L. A., Philosophical Magazine (1798-1977), 1924, vol. 48, p. 360 - 363
  作者：Compton, K. T.、Turner, L. A.

  DOI：——

  日期：——
• The rotational distribution in the mercury hydride molecules (<i>X</i> ²Σ⁺_1/2;<i>v</i>‘=0) produced in the reactions Hg(6 ³<i>P</i>₁)+H₂, HD, or D₂
  作者：N. Bras、J. Butaux、J. C. Jeannet、D. Perrin

  DOI：10.1063/1.451654

  日期：1986.7

  Initial rotational distributions of the vibrationless HgH or HgD molecules produced in the exoergic reactions of Hg (3P1) with H2, D2, and HD have been determined. No isotope effects have been observed. In the case of the reaction with HD the ratio [HgH(v″=0)]/[HgD (v″=0)] as well as the summed over all v″ ratio [HgH]/[HgD] have been measured.