iron nickel manganese oxide

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• 英文名称: iron nickel manganese oxide
• 英文别名: iron;manganese;nickel;tetrahydrate
• 化学式: FeMnNiO₄
• 分子量: 233.473
• InChiKey: VQEFIIHMMKCPNT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.31
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  manganese(II) nitrate 、 ferric nitrate 、 nickel(II) nitrate 在 氨 、 柠檬酸 作用下， 以 水 为溶剂， 反应 8.0h， 生成 iron nickel manganese oxide
  参考文献：
  名称：

  溶胶-凝胶合成纳米晶锰取代镍铁氧体的磁结构研究

  摘要：

  摘要 采用溶胶-凝胶法制备了纳米晶NiFe 2− x Mn x O 4 (2≥ x ≥0) 铁氧体。X 射线衍射图显示合成的化合物在所有组合物中都处于单相立方尖晶石晶格中。通过扫描电子显微镜研究所有样品的表面形貌。从透射电子显微镜和 X 射线衍射图测量的粒度证实了所制备粉末的纳米尺寸。元素分析采用能量色散X射线分析技术。研究了诸如饱和磁化强度、矫顽力和剩磁等磁特性与室温下 Mn 浓度增加的关系。随着Mn含量的增加，饱和磁化强度呈下降趋势。

  DOI：

  10.1016/j.jmmm.2016.04.090

文献信息

• Utilization of Nanospinel Fe_1.95Mn_0.05NiO₄ as the Adsorbent in Efficient Removal of Azo Dye Reactive Black 5 From Aqueous Solutions: Kinetic and Adsorption Studies
  作者：Iman Khosravi、Melika Eftekhar、Samad Shoghpour Bayraq

  DOI：10.1080/15533174.2013.769592

  日期：2014.2.7

  electron microscopy. The nanoparticles showed the excellent adsorption properties towards reactive black 5 as a reactive dye. The adsorption studies have been carried out at different pH values, various temperatures, and adsorbent doses. It was found that the removal process follows the second-order kinetics and the Freundlich adsorption isotherm.

  溶胶-凝胶法制备了尖晶石Fe 1.95 Mn 0.05 NiO 4纳米颗粒。尖晶石结构的特征在于差热分析，X射线粉末衍射，傅立叶红外光谱，透射电子显微镜和扫描电子显微镜。纳米颗粒显示出对作为反应性染料的反应性黑5的优异吸附性能。已经在不同的pH值，不同的温度和吸附剂剂量下进行了吸附研究。发现去除过程遵循二级动力学和弗氏吸附等温线。
• Mössbauer studies of Cu1−xNixFeMnO4 spinel ferrites
  作者：Kh. Roumaih、R.A. Manapov、E.K. Sadykov、A.V. Pyataev

  DOI：10.1016/j.jmmm.2004.09.116

  日期：2005.3

  diffraction measurements. Mossbauer spectra were recorded in 20–628 K temperature range. The spectra of all samples showed two well-resolved Zeeman patterns corresponding to A- and B-sites. At room temperature the hyperfine field increases with decreasing Cu concentration. The cation distribution obtained from analysis of Mossbauer spectra revealed a partially inverse spinel structure. The Curie temperature

  摘要 使用陶瓷技术制备了组成为(0⩽ x ⩽1) 的镍铜锰铁矿Cu 1− x Ni x FeMnO 4 。通过 X 射线粉末衍射测量证实了这些化合物的单相。穆斯堡尔谱记录在 20-628 K 温度范围内。所有样品的光谱都显示出两种解析良好的塞曼模式，分别对应于 A 位点和 B 位点。在室温下，超精细场随着铜浓度的降低而增加。从穆斯堡尔谱分析获得的阳离子分布揭示了部分反尖晶石结构。居里温度（TC）随着成分参数（x）的增加而增加。核 57 Fe 的比热 C p 是根据 Cu 0.5 Ni 0.5 FeMnO 4 和 NiFeMnO 4 的穆斯堡尔数据计算的。对于这些样品，研究了超精细参数的温度依赖性。亚晶格磁化 H ( T ) 在 0.47 T / TC 范围内服从三分之一幂律
• Feltz, A.; Toepfer, J.; Neidnicht, B., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Feltz, A.、Toepfer, J.、Neidnicht, B.

  DOI：——

  日期：——
• Studies on magnetic, dielectric and magnetoelectric behavior of (x) NiFe1.9Mn0.1O4 and (1−x) BaZr0.08Ti0.92O3 magnetoelectric composites
  作者：R.C. Kambale、P.A. Shaikh、C.H. Bhosale、K.Y. Rajpure、Y.D. Kolekar

  DOI：10.1016/j.jallcom.2009.09.080

  日期：2010.1

  In the present research work, the magnetoelectric (ME) composites of ferrite and ferroelectric phases with (x) NiFe1.9Mn0.1O4 and (1 - x) BaZr0.08Ti0.92O3 (where x = 0.10, 0.20 and 0.30) respectively were synthesized by the conventional ceramic method. The X-ray diffraction pattern of the composite reveals a spinel phase formation for the ferrite and perovskite phase formation for the ferroelectric phase without any other phase. The SEM micrographs of composites were taken to determine the average grain size and also to study the surface morphology. The effect of constituent phase variation on the B-H hysteresis behavior and the dielectric properties was examined. The dielectric constant shows usual dielectric dispersion behavior with increasing frequency which is due to the Maxwell-Wagner type surface interfacial polarization. From the ac conductivity study, it is confirmed that the conduction in the present composites is of small polaron type. The static magnetoelectric (ME) voltage coefficient developed on the surface of magnetoelectric material was measured as a function of applied dc magnetic field. The maximum ME conversion factor of 1.18 mV/cm Oe was observed for x = 0.10 composite. Such composites may be useful to fabricate the magnetic field sensors and applicable in many linear ME devices. (C) 2009 Elsevier B.V. All rights reserved.
• Effects of Cation Distribution and Oxidation State on the Electrical and Magnetic Properties of Ni_{1 – x}Cu_xFeMnO₄
  作者：V. V. Parfenov、Khaled M. Roumaih、R. A. Manapov、Sh. Z. Ibragimov

  DOI：10.1023/b:inma.0000008920.98386.7a

  日期：2003.12

  Ni1-xCuxFeMnO4(x=0-1) ferromanganites are prepared by solid-state reactions, and their structural, electrical, and magnetic properties were investigated. The results demonstrate that all of the synthesized materials are partially inverted spinels with cubic unit cells and are magnetic semiconductors. The temperature and frequency dependences of their transport properties are characteristic of hopping conduction. Mossbauer data and the results of electrical and magnetic measurements are used to assess the cation distribution in the ferromanganites studied, which are shown to contain Mn2+ in the A site and a mixture of Mn3+ and Mn4+ in the B site.