K[(μ-H)Cr2(CO)10] | 61453-56-3

• 英文名称: K[(μ-H)Cr2(CO)10]
• 英文别名: K[Cr2(CO)10(μ-H)]；K(μ-H)[Cr(CO)5]
• CAS: 61453-56-3
• 化学式: C₁₀HCr₂O₁₀*K
• 分子量: 424.202
• InChiKey: WFEDDSYLQRRGCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  K[(μ-H)Cr2(CO)10] 、 三溴化磷 以 四氢呋喃 为溶剂， 生成 pentacarbonyl(tribromophosphine)chromium(0)
  参考文献：
  名称：

  羰基金属衍生物的配体取代过程。4. 1 NMR研究氢化羰基铬酸盐与PX 3（X = Br，Cl）†

  摘要：

  在193 K，K + [HCr（CO）5 ] -（1当量）与PBr 3反应，得到Cr（CO）5 PH 3和K + [BrCr（CO）5 ] -。后者仅在高于253 K时与PBr 3反应，得到Cr（CO）5 PBr 3。在室温下，K + [HCr（CO）5 ] -（3当量）与PBr 3反应，得到Cr（CO）5 PH 3作为唯一的磷衍生物。对于K + [HCr（CO）5 ] -使用PCl 3。与此相反，K +（μ-H）[CR（CO）5 ] 2 -与PBR发生反应3仅在高于298 K，得到选择性的Cr（CO）5 PBR 3。

  DOI：

  10.1021/om0208063
• 作为产物：
  描述：

  potassium hydridopentacarbonylchromate 以 氘代四氢呋喃 为溶剂， 以0%的产率得到K[(μ-H)Cr2(CO)10]
  参考文献：
  名称：

  羰基金属衍生物的配体取代过程。3. 1羟基戊基羰基铬酸盐与膦的反应

  摘要：

  K的反应+ [HCR（CO）5 ] -与膦PR 3（R =的Et，PH，NME 2）在THF中在65℃下，得到二取代的复合物的反式-Cr（CO）4（PR 3）2分离收率57-70％。对于R ＝ Et和NMe 2，已经确定了反式Cr（CO）4（PR 3）2衍生物的X射线晶体结构。这些反应首先通过交换一个一氧化碳配体进行，生成单取代的氢化四羰基铬酸酯K + [HCr（CO）4 PR3 ] -，用NMR光谱法观察和表征R = Et和Ph。第二步包括取代K + [HCr（CO）4 PR 3 ] -的氢化物配体，得到双取代的衍生物反式Cr（CO）4（PR 3）2。这些配位体交换过程进行了讨论，并与与所述双核磷烷的反应桥接ķ +（μ-H）[CR（CO）5 ] 2 - 。

  DOI：

  10.1021/om020130b

文献信息

• Improved synthesis of KHCr(CO)5 and comparative coordination chemistry from KHCr(CO)5 and KHFe(CO)4
  作者：Jean-Jacques Brunet、Remi Chauvin、Bruno Donnadieu、Pascale Leglaye、Denis Neibecker

  DOI：10.1016/s0022-328x(98)00852-3

  日期：1998.11

  preparation of KHCr(CO)5 is described. The use of a potassium cation in the coordination chemistry of the [HFe(CO)4]− anion is completed and extended to the coordination chemistry of the [HCr(CO)5]− anion: CO-substitution by phosphites, phosphines and phosphinites, and H-abstraction by aminophosphines. Most of the observed differences in reactivity between KHFe(CO)4 and KHCr(CO)5 can be rationalized

  描述了一种选择性制备KHCr（CO）5的实用程序。钾离子在[HFe（CO）4 ] -阴离子的配位化学中的使用已完成，并扩展到[HCr（CO）5 ] -阴离子的配位化学：亚磷酸盐，膦和次膦酸酯的CO取代以及氨基膦对H的吸收。观察到的大多数KHFe（CO）4和KHCr（CO）5反应性差异可以通过更强的KHFe（CO）4酸度来合理化。
• On the coordination chemistry of corannulene, the smallest “buckybowl”
  作者：Michael W. Stoddart、John H. Brownie、Michael C. Baird、Hartmut L. Schmider

  DOI：10.1016/j.jorganchem.2005.04.044

  日期：2005.7

  A variety of methods, conventional and non-conventional, are used in attempts to prepare the compounds (eta(6)-corannulene)M(CO)(3) (M = Cr, Mo, W), all unsuccessful. Conventional methods are also utilized in attempts to prepare the compound [CpFe(eta(6)-corannulene)]PF6, but these result in mixtures of cationic CpFe(arene) complexes containing partially hydrogenated corannulene; similar results have been reported for other polyaromatic hydrocarbons. DFT calculations on the compound (eta(6)- corannulene)Cr(CO)(3) suggest that the (eta(6)-corannulene)-Cr linkage is only a few kcal/mol weaker than the corresponding bond in (eta(6)-benzene) Cr(CO)(3), implying that failures in syntheses arise from kinetic, not thermodynamic problems. (c) 2005 Elsevier B.V. All rights reserved.
• Assembling Process of Charged Nonanuclear Cationic Lanthanide(III) Clusters Assisted by Dichromium Decacarbonyl Hydride
  作者：Maurizio Addamo、Gabriella Bombieri、Elisabetta Foresti、M. Domenica Grillone、Maurizio Volpe

  DOI：10.1021/ic034700r

  日期：2004.3.1

  The reaction of Ln(acac)(3)(.)3H(2)O (Ln = Sm, Eu, Gd, Dy, Yb) with K[Cr-2(CO)(10)(mu-H)] at different molar ratios and solvents leads to the formation of nonanuclear lanthanide hydroxo acetylacetonate complexes of general formula [Ln(9)(OH)(10)(acac)(16)][HCr2(CO)(10)]. The compounds are isomorphous, and the common cationic cluster core consists of a novel square antiprismatic arrangement of nine Ln atoms connected by mu(3), mu(4) hydroxo bridges and/or by acetylacetonate ligands as it results from the single-crystal X-ray analysis of the Sm derivative for which the most suitable crystals were obtained.
• Darensbourg, Donald J.; Darensbourg, Marcetta Y.; Walker, Nyal, Inorganic Chemistry, 1981, vol. 20, # 6, p. 1918 - 1921
  作者：Darensbourg, Donald J.、Darensbourg, Marcetta Y.、Walker, Nyal

  DOI：——

  日期：——