(ferrocenylpyridin-2-ylmethyleneamine)(3,6-di-tert-butyl-o-catecholato)platinum(II) | 957829-51-5

• 英文名称: (ferrocenylpyridin-2-ylmethyleneamine)(3,6-di-tert-butyl-o-catecholato)platinum(II)
• CAS: 957829-51-5
• 化学式: C₃₀H₃₄FeN₂O₂Pt
• 分子量: 705.539
• InChiKey: DMXXSHGGZXQQSL-OENMPOSSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (ferrocenylpyridin-2-ylmethyleneamine)(3,6-di-tert-butyl-o-catecholato)platinum(II) 、 tris(p-bromophenylammoniumyl) hexachloroantimonate 以 二氯甲烷 为溶剂， 生成 (ferrocenylpyridin-2-ylmethyleneamine)dichloroplatinum(II) 、
  参考文献：
  名称：

  Ferrocene Linked to PtL₂ Fragments (L₂ = Cl₂, Fumaronitrile, 3,6-Di-tert-butylcatecholato):  A Spectroscopic and Theoretical Investigation of Redox Behavior and Charge Distributions

  摘要：

  The optical and redox properties of a ferrocene-appended diimine ligand (1) and its PtL2 complexes [L-2 = Cl-2 (2), fumaronitrile (3), 3,6-di-tert-butylcatecholato (4)] are reported. The chromophores are characterized by NMR, UV/vis, and IR spectroscopy as Well as cyclic voltarnmetry. Preparative oxidations to radical cations using "Magic Blue" [N(p-C6H4Br)(3)][SbCl6] or silver triflate in conjunction with UV/ vis, NMR, and EPR spectroscopy were used to probe the chloride-dependent redox chemistry of ligand I and platinum complexes 2-4. Density functional calculations were employed to corroborate geometric and electronic descriptions of 1-4 and their oxidized counterparts.

  DOI：

  10.1021/om700585v
• 作为产物：
  描述：

  tris(norbornene)platinum(0) 、 ferrocenylpyridin-2-ylmethyleneamine 、 3,6-di-tert-butylbenzene-1,2-diol 以 四氢呋喃 为溶剂， 以45%的产率得到(ferrocenylpyridin-2-ylmethyleneamine)(3,6-di-tert-butyl-o-catecholato)platinum(II)
  参考文献：
  名称：

  Ferrocene Linked to PtL₂ Fragments (L₂ = Cl₂, Fumaronitrile, 3,6-Di-tert-butylcatecholato):  A Spectroscopic and Theoretical Investigation of Redox Behavior and Charge Distributions

  摘要：

  The optical and redox properties of a ferrocene-appended diimine ligand (1) and its PtL2 complexes [L-2 = Cl-2 (2), fumaronitrile (3), 3,6-di-tert-butylcatecholato (4)] are reported. The chromophores are characterized by NMR, UV/vis, and IR spectroscopy as Well as cyclic voltarnmetry. Preparative oxidations to radical cations using "Magic Blue" [N(p-C6H4Br)(3)][SbCl6] or silver triflate in conjunction with UV/ vis, NMR, and EPR spectroscopy were used to probe the chloride-dependent redox chemistry of ligand I and platinum complexes 2-4. Density functional calculations were employed to corroborate geometric and electronic descriptions of 1-4 and their oxidized counterparts.

  DOI：

  10.1021/om700585v