5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl amine | 362011-05-0

• 英文名称: 5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl amine
• 英文别名: 2,6-bis[3,5-bis[2,6-di(propan-2-yl)phenyl]phenyl]aniline
• CAS: 362011-05-0
• 化学式: C₆₆H₇₉N
• 分子量: 886.36
• InChiKey: WWUKTBBJMBIBBY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.26
• 重原子数：
  67.0
• 可旋转键数：
  14.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  26.02
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl amine 在 二氯化二硫 、 三乙胺 作用下， 以 乙醚 为溶剂， 以85%的产率得到[2,6-Bis[3,5-bis[2,6-di(propan-2-yl)phenyl]phenyl]phenyl]imino-sulfanylidene-lambda4-sulfane
  参考文献：
  名称：

  A novel dendrimer-type m-terphenyl substituent for the kinetic stabilization of highly reactive species

  摘要：

  A novel m-terphenyl-based steric protection group (Bpq group) bearing a dendrimer-type framework was designed and successfully applied to the stabilization of the corresponding N-thiosulfinylaniline and arenesulfenyl iodide. The Bpq group was found to provide a very inert environment for the reactive functionality embedded in its clef. (C) 2001 Elsevier Science Ltd. Ail rights reserved.

  DOI：

  10.1016/s0040-4039(01)00871-1
• 作为产物：
  描述：

  2,4,6-溴碘苯 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 生成 5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl amine
  参考文献：
  名称：

  A novel dendrimer-type m-terphenyl substituent for the kinetic stabilization of highly reactive species

  摘要：

  A novel m-terphenyl-based steric protection group (Bpq group) bearing a dendrimer-type framework was designed and successfully applied to the stabilization of the corresponding N-thiosulfinylaniline and arenesulfenyl iodide. The Bpq group was found to provide a very inert environment for the reactive functionality embedded in its clef. (C) 2001 Elsevier Science Ltd. Ail rights reserved.

  DOI：

  10.1016/s0040-4039(01)00871-1