Re4(μ3-Se)4(TeCl2)4Cl8 | 186195-57-3

• 英文名称: Re4(μ3-Se)4(TeCl2)4Cl8
• CAS: 186195-57-3
• 化学式: Cl₁₆Re₄Se₄Te₄
• 分子量: 2138.32
• InChiKey: PLKVFGFJFMNZGC-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Re4(μ3-Se)4(TeCl2)4Cl8 、 N,N-二甲基甲酰胺 以 not given 为溶剂， 生成 Re4(μ3-Se)4(DMF)4Cl8
  参考文献：
  名称：

  Mironov, Yuri V.; Albrecht-Schmitt, Thomas E.; Ibers, James A., Inorganic Chemistry, 1997, vol. 36, p. 944 - 946

  摘要：

  DOI：
• 作为产物：
  描述：

  selenium 、 碲化氢 、 rhenium(V) chloride 以 not given 为溶剂， 生成 Re4(μ3-Se)4(TeCl2)4Cl8
  参考文献：
  名称：

  Two types of coordination polymers based on cluster anions [Re4Q4(CN)12]4− (Q=S, Se) and cations of rare-earth metals Ln3+: Syntheses and crystal structures

  摘要：

  The reactions of aqueous solutions of the tetrahedral cluster anions [Re(4)Q(4)(CN)(12)](4-) (Q= S. Sc) with lanthanide chlorides resulted in the crystallization of the formed compounds into two main structural types Ln(H2O)(4)(H2O)(2/3)Cl-1/3)(3)(Re(4)Q(4)(CN)(12)}2]center dot 2H(2)O (Ln= La-Cd. Q= S. Se) and K-0.5(H)(0.5)[{Ln(H2O)(4)} (Re4S4(CN)(12)}]center dot nH(2)O or (H)[{Ln(H2O)(4)}{Re4Se4(CN)(12)}]center dot 2H(2)O (Ln = Tb-Lu). Compounds of the first type crystallize in the hexagonal crystal system (space group P6(3)/m) and they have a three-dimensional polymeric structure; compounds of the second type crystallize in the orthorhombic crystal system (space group Cmcm) and they have a two-dimensional crystal structure due to the polymeric anion {[{Ln(H2O)(4)}{Re(4)Q(4)(CN)(12)}](-)}(infinity infinity). (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.02.051

文献信息

• Tetranuclear rhenium chalcochloride cluster complexes Cs3H[Re4Q4Cl12] · 3.33H2O (Q = Se and Te): Synthesis and structures
  作者：Yu. V. Mironov、O. A. Efremova、S. S. Yarovoi、V. E. Fedorov

  DOI：10.1134/s1070328409050017

  日期：2009.5

  tetranuclear cluster rhenium complexes Cs3H[Re4Q4Cl12] · 3.33H2O (Q = Te (I) and Se (II)) with the Cl atoms as terminal ligands were obtained and structurally characterized. The structures of complexes I and II were determined by X-ray diffraction analysis. Their isostructural crystals are monoclinic; space group C2, Z = 6; a = 26.403(8) Å, b = 16.495(5) Å, c = 11.744(3) Å, β = 91.25(2)°, V = 5113(2) Å3 (I); a

  得到了以Cl原子为末端配体的四核簇rh配合物Cs 3 H [Re 4 Q 4 Cl 12 ]·3.33H 2 O（Q = Te（I）和Se（II）），并进行了结构表征。配合物I和II的结构通过X射线衍射分析确定。它们的同构晶体是单斜晶的。空间组C 2，Z = 6；一个= 26.403（8）埃，b = 16.495（5），C ^ = 11.744（3），β= 91.25（2）°，V = 5113（2）埃3（我）; 一个= 26.573（3）埃，b = 16.461（3）埃，c ^ = 11.726（2）埃，β= 91.381（4）°，V = 5127.6（14）一种3（II）。
• First Examples of Chalcofluoride Rhenium Cluster Complexes with Cubane‐Like Anions [Re ₄ Q ₄ F ₁₂ ] ^4– (Q = S, Se)
  作者：Yuri V. Mironov、Spartak S. Yarovoi、Dmitry Y. Naumov、Natalia V. Kuratieva、Svetlana G. Kozlova、Arndt Simon、Vladimir E. Fedorov

  DOI：10.1002/ejic.200500130

  日期：2005.6

  group P with four formula units per cell [a = 10.6451(3) A, b = 14.6853(4) A, c = 16.9349(5) A, α = 66.8420(10)°, β = 84.8460(10)°, γ = 85.5740(10)°, V = 2421.69(12) A3 (T = 293 K)]. Hydrophilic terminal fluoride ligands of cluster anions are included in the hydrogen bond systems of their hydrate shells. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

  通过 Re4Q4(TeCl2)4Cl8 (Q = S, Se) 与熔融的 KHF2。两种化合物均已通过单晶 X 射线衍射方法进行了表征。化合物 1 在三角空间群 R 中结晶，每个单元有 24 个分子式单位 [a = b = 23.6503(3) A, c = 25.2697(7) A, V = 12240.6(4) A3 (T = 293 K)]；化合物 2 在单斜空间群 P 中结晶，每个单元有四个分子式单元 [a = 10.6451(3) A, b = 14.6853(4) A, c = 16.9349(5) A, α = 66.8420(10)°, β = 84.8460(10)°, γ = 85.5740(10)°, V = 2421.69(12) A3 (T = 293 K)]。簇阴离子的亲水末端氟化物配体包含在其水合物壳的氢键系统中。(© Wiley-VCH Verlag GmbH
• Tetrahedral chalcogeno thiocyanate cluster complexes [Re4Q4(SCN)12]4− (Q=S, Se, Te): synthesis and crystal structures
  作者：Yuri V. Mironov

  DOI：10.1016/s0277-5387(99)00382-4

  日期：2000.2

  The [Re(4)Q(4)(SCN)(12)](4-) (Q = S, Se, Te) anions were obtained by the reactions of neutral molecular clusters Re44QCl8(TeCl2)(4), Q = S, Se, Te, with melting KSCN. Crystal structures were determined for the isostructural compounds (Ph4P)(4)Re-44S(SCN)(12) (1), (Ph4P)(4)Re4Se4(SCN)(12) (2) and (Ph4As)(4)Re(4)T4(e)(SCN)(12) (3). Each contains an Re(4)Q(4) cubane-like cluster core with Re-Re distances in the ranges 2.762(3)-2.768(2) Angstrom (1), 2.799(2)-2.803(2) Angstrom (2) and 2.864(2)-2.877(2) Angstrom (3). The faces of the Re, units are symmetrically capped by triply bridging chalcogenide ligands Q(2-) (Q = S, Se, Te). (C) 2000 Elsevier Science Ltd All rights reserved.
• Novel inorganic polymeric compounds based on the Re4 chalcocyanide cluster complexes: synthesis and crystal structures of Mn2[Re4Se4(CN)12]·6H2O, Cd2[Re4Te4(CN)12]·6H2O, Cu2[Re4Te4(CN)12]·4H2O and K4Re4Se4(CN)12·6H2O
  作者：Yuri V. Mironov、Alexander V. Virovets、William S. Sheldrick、Vladimir E. Fedorov

  DOI：10.1016/s0277-5387(01)00735-5

  日期：2001.4

  Three new tetrahedral rhenium chalcocyanide cluster compounds, Mn-2[Re4Se4(CN)(12)]. 6H(2)O (1), Cd-2[Re4Te4(CN)(12)]. 6H(2)O (2) and Cu-2[Re4Te4(CN)(12)]. 4H(2)O (3), exhibiting polymeric structures have been synthesized by the treatment of molecular ionic cluster compounds K(4)Re(4)Q(4)(CN)(12) (Q = Se, Te) with aqueous solutions of Mn(NO3)(2), CdSO4 and CuCl2 in gel. The previously unknown starting compound K4Re4Se4(CN)(12). 6H(2)O (4) was obtained by the reaction of Re4Se4(TeCl2)(4)Cl-8 with KCN in water. All four compounds have been characterized by single-crystal X-ray diffraction. (C) 2001 Elsevier Science Ltd. All rights reserved.