[tetrakis(4-pyridyl)cyclopentadienone]cyclopentadienylcobalt | 191978-47-9

• 英文名称: [tetrakis(4-pyridyl)cyclopentadienone]cyclopentadienylcobalt
• 英文别名: [(C5H5)Co(C4(4-pyridyl)4CO)]
• CAS: 191978-47-9
• 化学式: C₃₀H₂₁CoN₄O
• 分子量: 512.516
• InChiKey: NDRBTKRAASIVQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  乙醚 、 [tetrakis(4-pyridyl)cyclopentadienone]cyclopentadienylcobalt 、 、 silver trifluoromethanesulfonate 以 氘代甲醇 、 甲醇 为溶剂， 反应 72.0h， 以25%的产率得到
  参考文献：
  名称：

  Ruthenium–Cobalt Bimetallic Supramolecular Cages via a Less Symmetric Tetrapyridyl Metalloligand and the Effect of Spacer Units

  摘要：

  The self-assembly of C-s-symmetric tetrapyridyl cobalt metalloligand 2 with three half-sandwich diruthenium acceptors, 3-5, led to the formation of A(4)D(2) (A = acceptor, D = donor) metallacages 6-8, as shown by ESI mass spectrometry, NMR spectroscopy, and X-ray crystallography. The solid-state structures of 6-8 revealed that the length of the acceptor unit greatly influences the molecular packing of these metallacages. Hence, in the solid state, 6-8 can be considered to have waterwheel-shaped, tweezer-shaped, and butterfly-like architectures, respectively.

  DOI：

  10.1021/jacs.5b07625
• 作为产物：
  描述：

  CpCo(CO)₂ 、 4-(2-吡啶-4-基乙炔基)吡啶 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 48.0h， 以45%的产率得到[tetrakis(4-pyridyl)cyclopentadienone]cyclopentadienylcobalt
  参考文献：
  名称：

  Ruthenium–Cobalt Bimetallic Supramolecular Cages via a Less Symmetric Tetrapyridyl Metalloligand and the Effect of Spacer Units

  摘要：

  The self-assembly of C-s-symmetric tetrapyridyl cobalt metalloligand 2 with three half-sandwich diruthenium acceptors, 3-5, led to the formation of A(4)D(2) (A = acceptor, D = donor) metallacages 6-8, as shown by ESI mass spectrometry, NMR spectroscopy, and X-ray crystallography. The solid-state structures of 6-8 revealed that the length of the acceptor unit greatly influences the molecular packing of these metallacages. Hence, in the solid state, 6-8 can be considered to have waterwheel-shaped, tweezer-shaped, and butterfly-like architectures, respectively.

  DOI：

  10.1021/jacs.5b07625

文献信息

• Microwave-Assisted Synthesis of Cyclopentadienyl–Cobalt Sandwich Complexes from Diaryl Acetylenes
  作者：Emily M. Harcourt、Shifra R. Yonis、Daniel E. Lynch、Darren G. Hamilton

  DOI：10.1021/om7011634

  日期：2008.4.1

  Sealed tube microwave dielectric heating of diaryl acetylenes with cyclopentadienyl cobalt dicarbonyl at elevated temperature in p-xylene provides access to metallocenes in both the cyclobutadiene (Ar(4)C(4)CoCp) and cyclopentadienone (Ar(4)C(4)(C=O)CoCp) families. When compared with the traditional thermal approach, the current method offers dramatically reduced reaction times and, especially with respect to cyclopentadienone complexes, increased yields. In the case of an especially bulky diarylacetylene the microwave approach allows access to a complex that cannot be readily obtained under traditional thermal conditions. An initial microwave-promoted Sonogashira coupling may be employed for in situ generation of the diarylacetylene, although lower yields of the metallocene complexes are ultimately obtained.
• Harrison, Robin M.; Brotin, Thierry; Noll, Bruce C., Organometallics, 1997, vol. 16, p. 3401 - 3412
  作者：Harrison, Robin M.、Brotin, Thierry、Noll, Bruce C.、Michl, Josef

  DOI：——

  日期：——