Pt(2-vinylpyridine-H)(Cl)(DMSO) | 1603827-93-5

• 英文名称: Pt(2-vinylpyridine-H)(Cl)(DMSO)
• CAS: 1603827-93-5；1604677-56-6
• 化学式: C₉H₁₂ClNOPtS
• 分子量: 412.799
• InChiKey: DGSZABSGJOFPLU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Pt(2-vinylpyridine-H)(Cl)(DMSO) 、 三苯基膦 以 丙酮 为溶剂， 反应 1.0h， 以90%的产率得到Pt(2-vinylpyridine-H)(Cl)(PPh3)
  参考文献：
  名称：

  Cyclometalated Complexes of Platinum(II) with 2‐Vinylpyridine

  摘要：

  AbstractThe electron‐rich platinum(II) derivatives [Pt(R)2(DMSO)2] (R = Me, Ph) react with 2‐vinylpyridine (L) to give the cyclometalated complexes [Pt(L–H)(R)(DMSO)] through C–H bond activation. Cyclometalation also occurs with [Pt(Me)(Cl)(DMSO)2]. From the starting compounds, a series of cyclometalated complexes was obtained and characterised by analytical and spectroscopic methods. The molecular structures of [Pt(L–H)(Me)(PPh3)] and [Pt(L–H)(Ph)(PCy3)] were solved by X‐ray diffraction analysis, and the results unambiguously demonstrate cyclometalation of 2‐vinylpyridine. The five‐membered cyclometalated ring is particularly stable, likely due to partial electronic delocalisation.

  DOI：

  10.1002/ejic.201400052
• 作为产物：
  描述：

  2-乙烯基吡啶 以 水 、 丙酮 、 甲苯 为溶剂， 反应 3.0h， 生成 Pt(2-vinylpyridine-H)(Cl)(DMSO)
  参考文献：
  名称：

  Cyclometalated Complexes of Platinum(II) with 2‐Vinylpyridine

  摘要：

  AbstractThe electron‐rich platinum(II) derivatives [Pt(R)2(DMSO)2] (R = Me, Ph) react with 2‐vinylpyridine (L) to give the cyclometalated complexes [Pt(L–H)(R)(DMSO)] through C–H bond activation. Cyclometalation also occurs with [Pt(Me)(Cl)(DMSO)2]. From the starting compounds, a series of cyclometalated complexes was obtained and characterised by analytical and spectroscopic methods. The molecular structures of [Pt(L–H)(Me)(PPh3)] and [Pt(L–H)(Ph)(PCy3)] were solved by X‐ray diffraction analysis, and the results unambiguously demonstrate cyclometalation of 2‐vinylpyridine. The five‐membered cyclometalated ring is particularly stable, likely due to partial electronic delocalisation.

  DOI：

  10.1002/ejic.201400052

文献信息

• Chirality Generated by Hindered Rotations in Platinum(II)‐Pyridine Complexes
  作者：Sergio Stoccoro、Alessandro Sini、Giacomo Senzacqua、Luca Maidich、Fabrizio Ortu、Antonio Zucca

  DOI：10.1002/ejic.202300649

  日期：2024.1.22

  A series of Pt(II) complexes with 2-alkylsubstituted pyridines display planar chirality due to the influence of the pyridine substituent, which enhances the rotational barrier around the Pt–N bond generating a couple of enantiomers. The chiral conformation is also stabilized by the presence of an axial Pt⋅⋅⋅H-C interaction.

  一系列具有 2-烷基取代吡啶的 Pt(II) 配合物由于吡啶取代基的影响而表现出平面手性，这增强了 Pt-N 键周围的旋转势垒，产生了一对对映体。轴向 Pt⋅⋅⋅HC 相互作用的存在也稳定了手性构象。