vinylacetylene, dicobalt-hexacarbonyl complex | 40671-80-5

• 英文名称: vinylacetylene, dicobalt-hexacarbonyl complex
• 英文别名: but-1-en-3-yne;carbon monoxide;cobalt
• CAS: 40671-80-5
• 化学式: C₁₀H₄Co₂O₆
• 分子量: 338.125
• InChiKey: PYYPKVONJZOYQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  vinylacetylene, dicobalt-hexacarbonyl complex 在 H₂SO₄ 作用下， 以 甲醇 为溶剂， 生成 n-C3H7CCo3(CO)9
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: Org.Verb.2, 3.1.3.5, page 152 - 167

  摘要：

  DOI：
• 作为产物：
  描述：

  乙烯基乙炔 、 dicobalt octacarbonyl 以 正戊烷 为溶剂， 以>99的产率得到vinylacetylene, dicobalt-hexacarbonyl complex
  参考文献：
  名称：

  Methylenecyclopropane in the [2+2+1]-cycloaddition reaction with dicobalt-hexacarbonyl complexes of acetylenes

  摘要：

  DOI：

  10.1007/bf00957787

文献信息

• A novel approach towards the preparation of functionalized alkyne derivatives via ArS-mediated AdE reaction of cobaltcarbonyl complexed conjugated enynes
  作者：Vasily V. Tumanov、Georgy V. Zatonsky、William A. Smit

  DOI：10.1016/j.tet.2010.01.060

  日期：2010.3

  A unified protocol of three-component coupling of arenesulfenyl chloride, dicobalthexacarbonyl complexed conjugated enynes. and nucleophiles of pi-donor type is applied for the synthesis of functionalized alkynes (C) 2010 Elsevier Ltd All rights reserved
• Discrete AdE reactions of dicobalthexacarbonyl complexes of conjugated enynes with participation of C-electrophiles and C-nucleophiles
  作者：G. S. Mikaelyan、A. S. Gybin、W. A. Smith

  DOI：10.1007/bf00951095

  日期：1984.2
• Short path to the synthesis of bi- and tricyclic compounds containing the 3-oxabicyclo[3.3.0]octene fragment from conjugated enynes by successive AdE reaction and [2+2+1]-cycloaddition
  作者：W. A. Smit、S. O. Simonyan、G. S. Mikaelyan、S. S. Mamyan、A. S. Gybin、A. S. Shashkov、R. Caple

  DOI：10.1007/bf00953615

  日期：1989.2
• μ-[3-4-η-(1-Alken-3-yne)hexacarbonyldicobalt complexes: Radical cyclocondensation mediated by manganese(III) acetate
  作者：Gagik G. Melikyan、Otto Vostrowsky、Walter Bauer、Hans Jürgen Bestmann

  DOI：10.1016/0022-328x(92)83037-i

  日期：1992.1

  A regioselective pathway for the radical reaction of 1-alken-3-ynes with beta-dicarbonyl compounds, mediated by Mn(OAc)3, can be achieved by protection of the substrate triple bond with a hexacarbonyldicobalt moiety. Dihydrofuran and hexahydrobenzofuran derivatives are formed by intermolecular oxidative cyclization of intermediate cobalt-complexed propargyl radicals.
• KIREEV, S. L.;SMIT, V. A.;NEFEDOV, O. M., IZV. AN CCCP. CEP. XIM.,(1989) N, S. 2061-2068
  作者：KIREEV, S. L.、SMIT, V. A.、NEFEDOV, O. M.

  DOI：——

  日期：——