dicyclopentadienylmethylzirconium fluoride | 100909-47-5

• 英文名称: dicyclopentadienylmethylzirconium fluoride
• CAS: 100909-47-5
• 化学式: C₁₁H₁₃FZr
• 分子量: 255.447
• InChiKey: IJPZAIVNTOPVNZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dicyclopentadienylmethylzirconium fluoride 以 not given 为溶剂， 生成 bis(cyclopentadienyl)dimethylzirconium(IV) 、 bis(η5-cyclopentadienyl)zirconium(IV) difluoride
  参考文献：
  名称：

  二环戊二烯基锆（IV）配合物的配体再分布反应

  摘要：

  双环戊二烯基锆化合物Cp 2 ZrR 2，Cp 2 ZrRX和Cp 2 ZrX 2的几个配体重新分布的速率随配体的变化而变化，顺序为F，I> Cl，Br和CH 3 > Ph。配体比类似的Ti化合物大得多。

  DOI：

  10.1016/0022-328x(85)87447-7
• 作为产物：
  描述：

  Cp2ZrMe(pentafluorophenyl) 、 六氟苯 以 氘代四氢呋喃 为溶剂， 生成 dicyclopentadienylmethylzirconium fluoride
  参考文献：
  名称：

  Generation of Perfluoropolyphenylene Oligomers via Carbon−Fluorine Bond Activation by Cp₂Zr(C₆F₅)₂:  A Dual Mechanism Involving a Radical Chain and Release of Tetrafluorobenzyne

  摘要：

  The thermal decomposition of Cp2Zr(C6F5)(2) in THF results in the slow formation of Cp2Zr(C6F5)F and tetrafluorobenzyne. The tetrafluorobenzyne is trapped by THF to give several products. The same reaction performed in the presence of durene or furan also results in the formation of Cp2Zr(C6F5)F and the respective Diels-Alder adducts of tetrafluorobenzyne. If Cp2Zr(C6F5)(2) is heated in the presence of C6F6, linear chains of perfluoroarenes are rapidly generated along with Cp2Zr(C6F5)F. The disappearance of Cp2Zr(C6F5)(2) is observed to slow dramatically after 30-80% completion, with the extent of reaction being inversely dependent on the concentration of C6F6. Dual mechanisms involving a rapid radical chain-and a slower tetrafluorobenzyne producing reaction are proposed to account for these observations.

  DOI：

  10.1021/ja991805d

文献信息

• Reactive cationic dicyclopentadienyl zirconium(IV) complexes
  作者：Richard F. Jordan、William E. Dasher、Scott F. Echols

  DOI：10.1021/ja00267a068

  日期：1986.4