[(CO)5Cr(P(CH(SiMe3)2)(C(Ph)=N))] | 207723-62-4

• 英文名称: [(CO)5Cr(P(CH(SiMe3)2)(C(Ph)=N))]
• 英文别名: pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphoshirene-κP]chromium(0)；[2-bis(trimethylsilyl)methyl-3-phenyl-2H-azaphosphirene-κP]pentacarbonylchromium(0)；[2-bis(trimethylsilyl)methyl-3-phenyl-2H-azaphosphirene-kappa.P]pentacarbonylchromium(0)；amino(phenyl)carbene chromiumpentacarbonyl；[(CO)₅Cr(P(CH(SiMe₃)₂)(C(Ph)=N))]
• CAS: 207723-62-4
• 化学式: C₁₉H₂₄CrNO₅PSi₂
• 分子量: 485.544
• InChiKey: ULKKNQXSTCGSJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(CO)5Cr(P(CH(SiMe3)2)(C(Ph)=N))] 以 氘代四氢呋喃 、 甲苯 为溶剂， 反应 3.0h， 生成 [lithium(12-crown-4)][bis(trimethylsilyl)methyl(chloro)phosphanido-κP]pentacarbonyl-chromium(0)
  参考文献：
  名称：

  Li / X膦基类五碳羰基金属配合物：结构和光谱性质的组合实验和理论研究

  摘要：

  的合成P -F膦金属配合物[（CO）5 μ{RP（H）F}]图2a - C ^（R = CH（森达3）2 ;一个：M = W; b：M =钼; Ç： M = Cr）是使用AgBF 4在P -Cl前体络合物[（CO）5 M {RP（H）Cl}] 3a – c中进行Cl / F交换所描述的；2 H-氮杂磷腈金属配合物[（CO）5 M {RP（C（Ph）═N}] 1a – c与[Et 3 NH] X的热反应生成配合物3a– c，4和5（M = W；a – c：X = Cl；4：X = Br；5：X = I）。在12-crown-4存在下，使用二异丙基氨基化锂使配合物2a - c，3a - c，4和5质子化，从而生成Li / X膦类金属配合物[Li（12-crown-4）（Et 2 O）n ] [（CO）5 M（RPX）] 6a – c，7a – c，8和9（6a – c：M = W，Mo，Cr;

  DOI：

  10.1021/ic302786v
• 作为产物：
  描述：

  [bis(trimethylsilyl)methylene]chlorophosphane 、 (aminobenzylidene)pentacarbonylchromium(0) 在 三乙胺 作用下， 生成 [(CO)5Cr(P(CH(SiMe3)2)(C(Ph)=N))]
  参考文献：
  名称：

  Recent Results on Synthesis and Ring Cleavage Reactions of 2H-Azaphosphirene Derivatives

  摘要：

  DOI：

  10.1080/10426509608545113

文献信息

• Synthesis of 2<i>H</i>-1,2-Azaphosphole Complexes by [3 + 2] Cycloaddition of Nitrilium Phosphane−Ylide Complexes with Various Alkynes:  Studies of the C-Substituent and Metal Effects on the Reaction Course
  作者：Hendrik Wilkens、Annette Ostrowski、Jörg Jeske、Frank Ruthe、Peter G. Jones、Rainer Streubel

  DOI：10.1021/om990537p

  日期：1999.12.1

  Thermal ring opening of [2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]pentacarbonylchromium(0), -molybdenum(0), or -tungsten(0) (1a−c) in the presence of three different alkynes, phenylacetylene, ethyl acetylenecarboxylate (EAC), and dimethyl acetylenedicarboxylate (DMAD) (i−iii), was investigated, using toluene (a) and benzonitrile (b) as solvents, whereby special emphasis was to determine

  [2-（双（三甲基甲硅烷基）甲基）-3-苯基-2 H-氮杂磷腈-κP ]五羰基铬（0），-钼（0）或-钨（0）（1a - c）的热开环使用甲苯（a）和苯甲腈（b）研究了三种不同的炔烃，苯乙炔，乙炔甲酸乙酯（EAC）和乙炔二甲酸二甲酯（DMAD）（i - iii）的存在）作为溶剂，因此特别需要确定[2 + 1] / [3 + 2]环加成产物比率和区域选择性对乙炔和瞬时形成的硝化膦-叶立德络合物的电子性质的依赖性。结果表明，后者的稳定性显然取决于C，N，P 1,3-偶极体系C取代基的供体能力。在甲苯中仅能获得1 H-膦络合物11a - c（ia），而当使用EAC（iia）和DMAD（iiia）作为捕集剂时，金属依赖性地形成1 H-磷腈和2 H的混合物H观察到-1,2-氮杂磷鎓配合物（M = Cr，W; iia，12a，c和13a，c ; iiia，4a，c和5c）或1 H-磷腈和二膦配合物的混合物（M
• Advances in 2<i>H</i>-Azaphosphirene Complex Chemistry
  作者：Rainer Streubel、Annette Ostrowski、Hendrik Wilkens、Siegfried Priemer、Udo Rohde

  DOI：10.1080/10426509708545614

  日期：1997.1.1
• Syntheses of 3-Phenyl-2H-Azaphosphirene Chromium and Molybdenum Complexes − First Evidence for Reaction Intermediates
  作者：Rainer Streubel、Frank Ruthe、Peter G. Jones

  DOI：10.1002/(sici)1099-0682(199805)1998:5<571::aid-ejic571>3.0.co;2-9

  日期：1998.5
• Click reactions of 2H-azaphosphirene chromium and molybdenum complexes and a surprisingly facile access to a 2H-1,4,2-diazaphosphole derivative
  作者：Holger Helten、Gregor Schnakenburg、Rainer Streubel

  DOI：10.1016/j.poly.2011.04.014

  日期：2011.6

  Ring expansion reactions of 2H-azaphosphirene chromium and molybdenum complexes 1a,b with dimethyl cyanamide, triflic acid, and, subsequently at ambient temperature, with triethylamine gave a mixture of the respective 2H-1,4,2-diazaphosphole complex 2a,b and the non-ligated heterocycle 3. If the deprotonation with NEt3 was carried out at low temperature, the selective formation of complexes 2a,b was observed, which were isolated in excellent yields and fully characterized (including single-crystal X-ray crystallography). Experimental and computational results revealed that the P, Cr and P, Mo bonds of 2H-1,4,2-diazaphosphole complexes are significantly weakened upon N-protonation of the heterocyclic ligand. When mixtures of 1a,b, TfOH, and Me2NCN were warmed to ambient temperature, the primarily formed N-protonated of 2H-1,4,2-diazaphosphole complexes 4a,b could be observed by P-31 NMR spectroscopy. The latter underwent decomplexation to give the N-protonated free ligand 5, which could be isolated and characterized by multinuclear NMR experiments. The neutral non-ligated heterocycle 3 was isolated from a one-pot reaction of 1b with TfOH and Me2NCN by adding NEt3 to a solution of intermediately formed 5. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.