| 688764-57-0

• CAS: 688764-57-0
• 化学式: C₁₁H₁₃FeN
• 分子量: 216.07
• InChiKey: CGGZUOUBHUCKIH-RUHRIWTCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 、 、 碘甲烷 以 neat (no solvent) 为溶剂， 生成 、 、
  参考文献：
  名称：

  Lithiation of 2,5-dimethylazaferrocene

  摘要：

  Reaction of 2,5-dimethylazaferrocene with see-BuLi/TMEDA in THF at -78 degreesC, followed by quenching with D2O brought about incorporation of deuterium into the Cp ring (54%), methyl groups (38%) and the pyrrolyl ss-position (8%). When benzyl chloride or p-methoxybenzaldehyde was used as quenchers products originated from the lateral lithiation were only formed, accompanied by recovered starting material. For this reaction a radical pathway is suggested. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.11.038
• 作为产物：
  描述：

  2,5-dimethylazaferrocene 、 重水 在 四甲基乙二胺 、 仲丁基锂 作用下， 以 四氢呋喃 、 环己烷 为溶剂， 以54%的产率得到
  参考文献：
  名称：

  Lithiation of 2,5-dimethylazaferrocene

  摘要：

  Reaction of 2,5-dimethylazaferrocene with see-BuLi/TMEDA in THF at -78 degreesC, followed by quenching with D2O brought about incorporation of deuterium into the Cp ring (54%), methyl groups (38%) and the pyrrolyl ss-position (8%). When benzyl chloride or p-methoxybenzaldehyde was used as quenchers products originated from the lateral lithiation were only formed, accompanied by recovered starting material. For this reaction a radical pathway is suggested. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.11.038