| 190122-17-9

• CAS: 190122-17-9
• 化学式: C₁₀H₁₅Cl₃InN₃O₃
• 分子量: 446.426
• InChiKey: LFDQQUYQDBWQRN-AZBGDINWSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 potassium oxalate 在 H₂O 作用下， 以 甲醇 、 水 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Mixed-ligand complexes of indium(III). Reactions of [InCl3(L1)(MeOH)] with bidentate ligands. Synthesis, characterization and X-ray structures of [In(L1)Cl(ox)(OH2)]·2H2O, [In(L1)Cl(mnt)]·MeOH and [In(pythio)3] [L1 = pyridine-2,6-bis(acetyloxime), ox2− = oxalate, mnt2− = 1,2-dicyanoethene-1,2-dithiolate, pythio− = pyridine-2-thiolate]

  摘要：

  [InCl3(L-1)(MeOH)] [L-1 = pyridine-2,6-bis(acetyloxime), 2,6-C5H3N(C2H3NOH)(2)] reacts with bidentate ligands by ligand exchange. A seven-coordinate complex of the composition [In(L-1)Cl(ox)(OH2)] is formed with potassium oxalate (K(2)ox). The oxalato ligand occupies the equatorial plane of a pentagonal bipyramid together with the tridentate amine oxime. With sodium 1,2-dicyanoethene-1,2-dithiolate (Na(2)mnt) the analogous reaction produces a six-coordinate mixed ligand complex, [In(L-1)Cl(mnt)], which has a distorted octahedral coordination sphere. Ligands which form four-membered chelate rings like dialkyldithiocarbamates, R(2)dtc(-), or pyridine-2-thiolate, pythio(-), are able to replace all ligands of [InCl3(L-1)(MeOH)] to form neutral tris chelates. The structure of [In(pythio)(3)] has been elucidated showing a strong distortion of the coordination polyhedron from the idealized octahedral geometry. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00536-0
• 作为产物：
  描述：

  2,6-diacetylpyridine dioxime 、 氯化铟 在 MeOH 作用下， 以 甲醇 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Indium(III) complexes with tridentate nitrogen donor ligands. Synthesis, characterization and crystal structure of complexes with pyridine-2,6-bis(acetyloxime) and 2,6-bis(1-phenyliminoethyl)pyridine

  摘要：

  2,6-Bis (acetyloxime)pyridine, 2,6-C5H3N(C2H3NOH)(2) (L-1), reacts with indium(III) chloride in methanol to give the seven-coordinate complex [InCl3(L-1)(MeOH)]. The structurally similar Schiff base ligand 2,6-bis(1-phenyliminoethyl)pyridine (L-2), 2,6-C5H3N(C2H3NC6H5)(2), however, forms a six-coordinate indium(III) complex of the composition [InCl3(L-2)]. The In-N bond distances are longer by 0.03-0.12 Angstrom in the seven-coordinate compound compared with those in the Schiff base complex. The MeOH ligand in [InCl3(L-1)(MeOH)] can be replaced by Cl- or H2O to give the complex anion [InCl4(L-1)](-) and [InCl3(L-1)(OH2)], respectively. The pentagonal-bipyramidal coordination environment of the metal is preserved during these reactions. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00553-0