[(2,6-bis(benzimidazol-2-yl)pyridine)RhCl3] | 187244-72-0

• 英文名称: [(2,6-bis(benzimidazol-2-yl)pyridine)RhCl3]
• 英文别名: [(2,6-bis(benzimidazol-2-yl)pyridine)RhCl₃]
• CAS: 187244-72-0
• 化学式: C₁₉H₁₃Cl₃N₅Rh
• 分子量: 520.61
• InChiKey: PUUNYUFLRWRUGQ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(2,6-bis(benzimidazol-2-yl)pyridine)RhCl3] 、 sodium iodide 以 乙醇 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Reactions of rhodium and iridium salts with multidentate N-heterocycles

  摘要：

  Complexes of rhodium and iridium of the types MX(3)L, MX(CO)(2)L and MX(3)(CO)L (X = halide) containing multidentate N-heterocycles (L),2,6-bis(benzimidazolyl)pyridine (bBzlH(2)py) and 2,6-bis(N-methylbenzimidazolyl)pyridine (bBzlMe(2)py) have been prepared and characterized by IR, electronic and H-1 and C-13 NMR spectral data. RhX(CO)(2)L, on treatment with alcoholic solvents or DMF undergoes reversible decarbonylation to produce RhXL . 2H(2)O. Passage of NO or O-2 through the carbonyl suspended in hot 2-methoxyethanol releases CO2. Copyright (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00368-3
• 作为产物：
  描述：

  氯化铑(三水) 、 2,6-双(2-苯并咪唑基)吡啶 以 乙醇 为溶剂， 生成 [(2,6-bis(benzimidazol-2-yl)pyridine)RhCl3]
  参考文献：
  名称：

  Reactions of rhodium and iridium salts with multidentate N-heterocycles

  摘要：

  Complexes of rhodium and iridium of the types MX(3)L, MX(CO)(2)L and MX(3)(CO)L (X = halide) containing multidentate N-heterocycles (L),2,6-bis(benzimidazolyl)pyridine (bBzlH(2)py) and 2,6-bis(N-methylbenzimidazolyl)pyridine (bBzlMe(2)py) have been prepared and characterized by IR, electronic and H-1 and C-13 NMR spectral data. RhX(CO)(2)L, on treatment with alcoholic solvents or DMF undergoes reversible decarbonylation to produce RhXL . 2H(2)O. Passage of NO or O-2 through the carbonyl suspended in hot 2-methoxyethanol releases CO2. Copyright (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00368-3

文献信息

• Photoinduced Electron and Energy Transfer and pH-Induced Modulation of the Photophysical Properties in Homo- and Heterobimetallic Complexes of Ruthenium(II) and Rhodium(III) Based on a Heteroditopic Phenanthroline–Terpyridine Bridge
  作者：Dinesh Maity、Chanchal Bhaumik、Srikanta Karmakar、Sujoy Baitalik

  DOI：10.1021/ic400449c

  日期：2013.7.15

  occurs in all three unsymmetrical homobimetallic complexes. On the other hand, for both heterometallic dyads, an efficient intramolecular photoinduced electron transfer from the excited ruthenium moiety to the rhodium-based unit takes place. The rate constants for the energy- and electron-transfer processes have been determined by time-resolved emission spectroscopy. The influence of the pH on the absorption

  组成[[bpy）2 Ru II（phen-Hbzim-tpy）Ru II（tpy / tpy -PhCH 3 / H 2 pbbzim）]的同金属和异双金属配合物] 4+和[[bpy）2 Ru II（phen-Hbzim） -tpy）Rh III（tpy -PhCH 3 / H 2 pbbzim）] 5+，其中phen-Hbzim-tpy = 2- [4-（2,6-dipyridin-2-ylpyridin-4-yl）phenyl] -1 H-咪唑[4,5- f ] [1,10]菲咯啉，bpy = 2,2'-联吡啶，tpy = 2,2'：6'，2”-叔吡啶，tpy-PhCH 3 = 4'-（ 4-甲基苯基）-2,2'：6'，2''-叔吡啶和H 2已合成pbbzim = 2,6-双（苯并咪唑-2-基）吡啶，并通过元素分析，电喷雾电离质谱和1 H NMR光谱进行了表征。这些双金属配合物的吸收光