(μ-Br)2[κ(2)-N2',C1-1-Pd-2-((2'-NH2C6H4)C6H4)]2 | 182628-73-5

• 英文名称: (μ-Br)2[κ(2)-N2',C1-1-Pd-2-((2'-NH2C6H4)C6H4)]2
• 英文别名: (μ-Br)2[Pd(κ2-N2',C1-2-(2'-NH2C6H4)C6H4)]2
• CAS: 182628-73-5
• 化学式: C₂₄H₂₀Br₂N₂Pd₂
• 分子量: 709.084
• InChiKey: RPMIJUBBLONMGE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (μ-Br)2[κ(2)-N2',C1-1-Pd-2-((2'-NH2C6H4)C6H4)]2 、 1,4-dimethyl but-2-enedioate 以 氯仿 为溶剂， 生成 (μ-Br)2[κ(2)-N2',C1-1-Pd-2-((2'-NH2C6H4)C6H4)-cis-1,2-(CO2Me)2-C=C]2
  参考文献：
  名称：

  Monoinsertion of but-2-ynedioic acid dimethyl ester into palladium–carbon σ bonds of cyclopalladated compounds derived from biphenyl-2-ylamine: X-ray molecular structure of biphenyl-2-yl-(2,4,6-trimethoxy-benzylidene)-amine

  摘要：

  Dinuclear cyclopalladated compounds (mu-Br)2[kappa(2)-N2',Cl-1-Pd-2-{(2'-RCH=NC6H4)C6H4}](2) [1a (R = 2,4,6-trimethoxyphenyl), 1b (R = 2,6-dichlorophenyl) and 1c (R = 2,6-difluorophenyl)] and (mu-Br)(2)[kappa(2)-N-2',Cl-1-Pd-2-{(2'-NH2C6H4)C6H4}](2) (1d) reacted with but-2-ynedioic acid dimethyl ester (molar ratio 1-2) to afford the dinuclear cyclopalladated compounds (mu-Br)(2)[kappa(2)-N2',Cl-1-Pd-2-{(2'-RCH=NC6H4)C6H4}-cis-1,2-(CO2Me)(2)-C=C](2) [2a (R = 2,4,6-trimethoxyphenyl), 2b (R = 2,6-dichlorophenyl) and 2c (R = 2,6-difluorophenyl)] and (mu-Br)(2)[kappa(2)-N2',Cl-1-Pd-2-{(2'-NH2C6H4)C6H4}-cis-1,2-(CO2Me)(2)-C=C](2) (2d), which derived from the monoinsertion of the alkyne into the palladium-carbon sigma bonds of the cyclopalladated dimers 1. Compounds 2a and 2b reacted with PPh3 (molar ratio 1-4) to give a mixture of the mononuclear compound trans-N,P-{[kappa(2)-N2',Cl-1-Pd-2-{(Z-2'-RCH=NC6H4)C6H4}-cis-1,2-(CO2Me)(2)-C=C]Br(PPh3)} and trans-P,P-{[kappa(1)-Cl-1-Pd-2-{(E-2'-RCH=NC6H4)C6H4)-cis-1,2(CO2Me)(2)-C=C]Br(PPh3)(2)} in a molar ratio of 1-2 and ca. 1-12, respectively. Compound 2c reacted with PPh3 in a molar ratio 1-4 giving trans-P,P-{[kappa(1)-Cl-1-Pd-2-{(E-2'-RCH=NC6H4)C6H4}-cis-1,2-(CO2Me)(2)-C=C]Br(PPh3)(2)} (R=2,6-difluorophenyl)-(compound 4c) and compound 2d reacted with PPh3 in a molar ratio of 1-2, affording the mononuclear cyclopalladated compound trans-N,P-{[cis-kappa(2) -N2',Cl-1-Pd-2-{(2'-NH2C6H4)C6H4}-1,2-(CO2Me)(2)-C=C]Br(PPh3)} (compound 3d). Notably, the P-31{H-1} NMR of compounds 4 produced an AB spin system, showing that compounds 4 were chiral. In addition, we report the X-ray molecular structure of the E isomer of the free Schiff base a [biphenyl-2-yl-(2,4,6-trimethoxy-benzylidene)-amine]. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.08.002
• 作为产物：
  描述：

  palladium diacetate 、 2-氨基联苯 、 lithium bromide 以 溶剂黄146 、 丙酮 为溶剂， 以39%的产率得到(μ-Br)2[κ(2)-N2',C1-1-Pd-2-((2'-NH2C6H4)C6H4)]2
  参考文献：
  名称：

  再谈2-苯基苯胺的环钯反应

  摘要：

  2-苯基苯胺与甲苯中的Pd（OAc）2在室温下以一对一的摩尔比反应24小时，并与PdCl 2，NaCl和NaOAc体系以1（2-苯基苯胺）：1（PdCl 2）：2（氯化钠）：1（的NaOAc）在甲醇中在室温下1周，得到双核环钯化合物（μ-X摩尔比）2 [{钯κ 2 - N2 '，C1 -2-（2'- NH 2 C 6 H 4）C 6 H 4 }] 2 [ 1a（X = OAc）和1b（X = Cl）]高产率。此外，2-苯基苯胺与Pd（OAc）之间的反应2在60℃下4小时在酸乙酸一个对一摩尔比，然后用溴化锂的复分解反应时，双核环钯化合物的允许隔离（μ-溴）2 [钯{κ 2 - N2 '，C1 -2-（2'-NH 2 C 6 H 4）C 6 H 4 }] 2（1c）以中等收率。并行处理，但使用monodeuterated乙酸（DOAc）如在cyclopalladation反应溶剂，化合物的混合物的允许隔离1C，1C

  DOI：

  10.1016/j.jorganchem.2004.07.067