(1-indenyl)ferrocene | 140175-34-4

• 英文名称: (1-indenyl)ferrocene
• 英文别名: (3-ferrocenyl)indene；(3-indenyl)ferrocene；1-indenylferrocene；3-ferrocenylindene
• CAS: 140175-34-4
• 化学式: C₁₉H₁₆Fe
• 分子量: 300.183
• InChiKey: SWUFWAKYUFFOTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (1-indenyl)ferrocene 、 重水 在 n-BuLi 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以90%的产率得到monodeuterated (1-indenyl)ferrocene
  参考文献：
  名称：

  单（环戊二烯基）-和双（环戊二烯基）取代的二茂铁的合成与结构

  摘要：

  The reactions of the cyclopentenones 3,4-dimethylcyclopentenone, 1-indanone, and 2-indanone with mono- and dilithioferrocene lead to the synthesis of cyclopentadienyl-substituted ferrocenes: (3,4-dimethyl-cyclopenta-1,3-dienyl)ferrocene (1), (1-indenyl)ferrocene (3), (2-indenyl)ferrocene (4), and 1,1'-bis(3,4-dimethylcyclopenta-1,3-dienyl)ferrocene (2). The crystal structure of compound 2 was determined. The crystal data are as follows: C24H26Fe, triclinic, P1BAR, a = 7.561 (2) angstrom, b = 10.738 (2) angstrom, c = 13.005 (3) angstrom = 102.05 (3)-degrees, beta = 104.29 (3)-degrees, gamma- 108.84 (3)-degrees, V = 919.1 (4) angstrom3, Z = 2, R = 0.0279, and R(W) = 0.0398 on the basis of 2336 reflections with F greater-than-or-equal-to 4-sigma-(F). It displays an unusual cofacial arrangement of the two 3,4-dimethylcyclopenta-1, 3-dienyl rings. The lithium salt of 1 reacts with FeCl2 to give the triferrocenyl bis(1-ferrocenyl-3,4-dimethylcyclopentadienyl)ferrocene (5). The reaction of the dilithium salt of 2 with FeCl2 yields a mixture of polymeric ferrocenes.

  DOI：

  10.1021/om00041a019
• 作为产物：
  描述：

  二茂铁 、 1-茚酮 在 BuLi 作用下， 以 四氢呋喃 、 乙醚 、 正戊烷 为溶剂， 以46%的产率得到(1-indenyl)ferrocene
  参考文献：
  名称：

  Synthesis of (ferrocenyl-indenyl)cyclopentadienyliron compounds with and without a bridging group via a CpFe transfer reaction

  摘要：

  A series of {ferrocenyl-indenyl}cyclopentadienyliron complexes with and without a spacer (spacer = -C6H4-, -C=C-, -CH2-) was prepared using a CpFe transfer reaction. All the compounds studied showed two successive one-electron transfers. The Delta E-1/2 values depend upon the spacer in the order: acetylenic > methylene > phenylene. The complex {1-(C5H5FeC5H4)-indenyl} FeCp (1b) was characterized by X-ray diffraction. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00368-5

文献信息

• Ferrocene bridged and substituted tetramethylcyclopentadienyl (or indenyl) carbonyl complexes of iron, ruthenium, and molybdenum
  作者：Jin Lin、Baiquan Wang、Shansheng Xu、Haibin Song

  DOI：10.1016/j.jorganchem.2006.01.041

  日期：2006.5

  corresponding trinuclear and tetranuclear complexes Fc[(C5Me4)M(CO)]2(μ-CO)]2 [M = Ru (2), Fe (3)], Fc[(C5Me4)Mo(CO)3]2 (4) and [(C5H5 FeC5H4)C5Me4M(CO)]2(μ-CO)2 [M = Ru (6), Fe (7)], [(C5H5FeC5H4)C5Me4Mo(CO)3]2 (8). Reactions of (3-indenyl)ferrocene (9) with Ru3(CO)12 or Fe(CO)5 in refluxing xylene or heptane, also gave the corresponding tetranuclear metal complexes [(C5H5FeC5H4)C9H6M(CO)]2(μ-CO)2 [M = Ru

  二茂铁桥联和取代的四甲基环戊二烯配体1,1'-Fc（C 5 Me 4 H）2（1）（Fc = 1,1'-二茂铁基）和（C 5 H 5 FeC 5 H 4）C 5 Me 4的反应H（5）与Ru 3（CO）12，Fe（CO）5和Mo（CO）3（CH 3 CN）3在回流的二甲苯中得到相应的三核和四核配合物Fc [（C 5 Me 4）M（ CO）] 2（μ-CO）] 2[M = Ru（2），Fe（3）]，Fc [（C 5 Me 4）Mo（CO）3 ] 2（4）和[（C 5 H 5 FeC 5 H 4）C 5 Me 4 M（ CO）] 2（μ-CO）2 [M = Ru（6），Fe（7）]，[（C 5 H 5 FeC 5 H 4）C 5 Me 4 Mo（CO）3 ] 2（8）。（3-茚基）二茂铁（9）与Ru 3（CO）12或Fe（CO）5在回流的二甲苯或庚烷中的反应也得到了相应的四核金属配合物[（C 5
• Redox-controlled syndio-specific polymerization of styrene catalyzed by ferrocenyl functionalized half-sandwich scandium complexes
  作者：Yi Zhong、Min Li、Meng Deng、Mingliang Gong、Hongzhen Xie、Yunjie Luo

  DOI：10.1039/d0dt03680c

  日期：——

  bis(o-dimethylaminobenzyl) complex [Fc(1-C9H6)]Sc(CH2C6H4NMe2-o)2 (1) in 89% isolated yield. This complex was characterized by elemental analysis, FT-IR spectroscopy, NMR spectroscopy and single-crystal X-ray diffraction. Treatment of 1 with 1 equiv. of [Ph3C][B(C6F5)4] in THF generated the THF-coordinated cationic half-sandwich scandium mono(o-dimethylaminobenzyl) complex [Fc(1-C9H6)]Sc(CH2C6H4NMe2-o)}[B(C6F5)4]}

  氧化还原控制的聚合是精确构建聚合物材料微观结构的新的有效策略之一，因此在化学界越来越受到关注。1当量的ScCl 3的盐易位。Fc（1-C 9 H 6）Li（其中Fc ＝二茂铁基），然后加入2当量。在室温下于THF中分离LiCH 2 C 6 H 4 NMe 2 - o得到二茂铁基官能化的半三明治scan双（邻-二甲基氨基苄基）络合物[Fc（1-C 9 H 6）] Sc（CH 2 C 6 H 4NMe 2 - o）2（1），分离产率为89％。通过元素分析，FT-IR光谱，NMR光谱和单晶X射线衍射对该复合物进行了表征。治疗1与1个当量。THF中的[Ph 3 C] [B（C 6 F 5）4 ]生成THF配位的阳离子半三明治-单（邻二甲基氨基苄基）络合物[Fc（1-C 9 H 6）] Sc（CH 2 C 6 H 4 NMe 2 - o）} [B（C 6 F 5）4 ]}（2-THF 2）。原位在1
• Structure of Z- and E-2-bromo-1-ferrocenyl-1-phenylcyclopropanes and 3-ferrocenyl-3-phenylcyclopropene and their three-membered ring opening reactions
  作者：Elena I. Klimova、B. Tatiana Klimova、Lena Ruíz Ramírez、G. Marcos Martínez、T. Cecilio Alvarez、P. Georgina Espinosa、Ruben A. Toscano

  DOI：10.1016/s0022-328x(97)00371-9

  日期：1997.1

  ring-opening reactions in Z- and E-2-bromo-1-ferrocenyl-1-phenylcyclopropanes and 3-ferrocenyl-3-phenylcyclopropene were studied. It was found that the three-membered ring of the monobromides is opened when treated with AlCl3, while that of cyclopropene is opened when boiled in toluene. X-ray structural data of E-2-bromo-1-ferrocenyl-1-phenyIcyclopropane and 3-ferrocenyl-3-phenyl-cyclopropene mono crystals

  研究了Z-和E -2-溴-1-二茂铁基-1-苯基环丙烷和3-二茂铁基-3-苯基环丙烯中的开环反应。发现当用AlCl 3处理时，一溴化物的三元环是打开的，而当在甲苯中沸腾时，环丙烯的三元环是打开的。给出了E -2-溴-1-二茂铁基-1-苯基环丙烷和3-二茂铁基-3-苯基-环丙烯单晶的X射线结构数据。
• Synthesis and some chemical transformations of 3-ferrocenyl-3-phenylcyclopropene
  作者：E. I. Klimova、C. Alvarez Toledano、M. Martinez Garcia、L. Gomez Lara、N. N. Meleskonkova、I. G. Bolesov

  DOI：10.1007/bf01435791

  日期：1996.3

  Crystalline 3-ferrocenyl-3-phenylcyclopropene was obtained by dehydrobromination of 2-bromo-l-ferrocenyl-l-phenylcyclopropane with potassiumtert-butoxide in dimethyl sulfoxide. The compound synthesized undergoes catalytic hydrogenation to l-ferrocenyl-I-phenylcyclopropane, reacts with 1,3-diphenylisobenzofuran to give the expected product of stereospecific [4+2[-cycloaddition and 3-ferrocenylindene

  通过在二甲基亚砜中用叔丁醇钾对 2-溴-1-二茂铁基-1-苯基环丙烷进行脱溴化氢得到结晶的 3-二茂铁基-3-苯基环丙烯。合成的化合物经过催化加氢生成 l-二茂铁基-I-苯基环丙烷，与 1,3-二苯基异苯并呋喃反应得到预期的立体有择 [4+2[-环加成和 3-二茂铁基] 产物，并且在用超强酸处理得到 3-二茂铁作为主要产物。给出了1-二茂铁基-1-苯基环丙烷和3-二茂铁基-3-苯基环丙烯与1,3-二苯基异苯并呋喃的二烯加合物的单晶X射线衍射分析数据。
• Scott, Peter; Rief, Ursula; Diebold, Josef, Organometallics, 1993, vol. 12, # 8, p. 3094 - 3101
  作者：Scott, Peter、Rief, Ursula、Diebold, Josef、Brintzinger, Hans H.

  DOI：——

  日期：——