lambda~2~-Stannane--zirconium (2/1) | 12166-60-8

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: lambda~2~-Stannane--zirconium (2/1)
• 英文别名: λ2-stannane;zirconium
• CAS: 12166-60-8
• 化学式: Sn₂Zr
• 分子量: 328.644
• InChiKey: ISAZMZHQRLSWNB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.83
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  锆 、 lambda~2~-Stannane--zirconium (2/1) 、 生成
  参考文献：
  名称：

  The lead-zirconium system: binary phases and a series of interstitial compounds of the host Zr5Pb3

  摘要：

  The Pb-Zr system contains the phases Zr(approximately 5.8)Pb (Cr3Si-type), Zr5Pb3 (Mn5Si3) and Zr5Pb4 (Ti5Ga4). Zr5Pb4 as a substoichiometric region above approximately 800-degrees-C, extending to about Zr5Pb3.65 at 1000-degrees-C. Reactive powder sintering in sealed Ta containers at 1000-1350-degrees-C is the most effective route for the synthesis of pure phases of both the binaries and the interstitial derivatives Zr5Pb3Z. Twenty examples of the latter were obtained with Z = Al, Si, P, S, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Ag, Cd, In, Sn, Sb, Te, (Pb), (second period Z were not investigated). Single crystals for Z = Al, Cd, Zn, Pb0.87, Pb0.94 were obtained by metal flux or vapor phase transport reactions, and the last three were quantified by X-ray crystallography. Volume trends as a function of group and period follow metal/covalent radii trends for Z fairly well.

  DOI：

  10.1016/0925-8388(93)90402-9
• 作为产物：
  描述：

  tin 、 锆 生成 lambda~2~-Stannane--zirconium (2/1)
  参考文献：
  名称：

  The lead-zirconium system: binary phases and a series of interstitial compounds of the host Zr5Pb3

  摘要：

  The Pb-Zr system contains the phases Zr(approximately 5.8)Pb (Cr3Si-type), Zr5Pb3 (Mn5Si3) and Zr5Pb4 (Ti5Ga4). Zr5Pb4 as a substoichiometric region above approximately 800-degrees-C, extending to about Zr5Pb3.65 at 1000-degrees-C. Reactive powder sintering in sealed Ta containers at 1000-1350-degrees-C is the most effective route for the synthesis of pure phases of both the binaries and the interstitial derivatives Zr5Pb3Z. Twenty examples of the latter were obtained with Z = Al, Si, P, S, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Ag, Cd, In, Sn, Sb, Te, (Pb), (second period Z were not investigated). Single crystals for Z = Al, Cd, Zn, Pb0.87, Pb0.94 were obtained by metal flux or vapor phase transport reactions, and the last three were quantified by X-ray crystallography. Volume trends as a function of group and period follow metal/covalent radii trends for Z fairly well.

  DOI：

  10.1016/0925-8388(93)90402-9

文献信息

• Investigation of the reaction progress between stannous chloride and zirconium in molten LiCl–KCl
  作者：Yanqing Cai、Hongxia Liu、Qian Xu、Qiushi Song、Huijun Liu

  DOI：10.1039/c5ra02476e

  日期：——

  LiCl–KCl–ZrCl₄ melt was prepared by displacement reaction between SnCl₂ and Zr, and the reaction progress was electrochemically monitored.

  通过 SnCl2 和 Zr 之间的置换反应制备了 LiCl-KCl-ZrCl4 熔体，并通过电化学监测反应进程。
• The lead-zirconium system: binary phases and a series of interstitial compounds of the host Zr5Pb3
  作者：Young-Uk Kwon、John D. Corbett

  DOI：10.1016/0925-8388(93)90402-9

  日期：1993.1

  The Pb-Zr system contains the phases Zr(approximately 5.8)Pb (Cr3Si-type), Zr5Pb3 (Mn5Si3) and Zr5Pb4 (Ti5Ga4). Zr5Pb4 as a substoichiometric region above approximately 800-degrees-C, extending to about Zr5Pb3.65 at 1000-degrees-C. Reactive powder sintering in sealed Ta containers at 1000-1350-degrees-C is the most effective route for the synthesis of pure phases of both the binaries and the interstitial derivatives Zr5Pb3Z. Twenty examples of the latter were obtained with Z = Al, Si, P, S, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Ag, Cd, In, Sn, Sb, Te, (Pb), (second period Z were not investigated). Single crystals for Z = Al, Cd, Zn, Pb0.87, Pb0.94 were obtained by metal flux or vapor phase transport reactions, and the last three were quantified by X-ray crystallography. Volume trends as a function of group and period follow metal/covalent radii trends for Z fairly well.