Ge^ICl

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 类金属盐
• 英文名称: Ge^ICl
• 英文别名: germanium chloride；germane;hydrochloride
• 化学式: ClGe
• 分子量: 108.043
• InChiKey: HGIVOUVRVKQVQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.03
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Ge^ICl 以 neat (no solvent) 为溶剂， 生成 锗烷
  参考文献：
  名称：

  Baronetzky, E., Diss. Aachen T. H. 1953, S. 1/52

  摘要：

  DOI：
• 作为产物：
  描述：

  四氯化锗 在 H₂ 作用下， 以 neat (no solvent) 为溶剂， 生成 Ge^ICl
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ge: SVol., 111, page 512 - 513

  摘要：

  DOI：

文献信息

• GeCp^big₂[Cp^big= C₅(CH₂C₆H₄-<i>i</i>Pr)₅]: A Flexible Sandwich Molecule
  作者：Dominik Naglav、Briac Tobey、Sjoerd Harder、Andreas Schnepf

  DOI：10.1002/zaac.201200242

  日期：2013.2

  GeCpbig2 (1) [Cpbig = C5(CH2C6H4-iPr)5] was synthesized by a reaction of KCpbig either with a GeCl solution or GeCl2 and was obtained as colorless crystals. The molecular structure of 1 was determined by X-ray diffraction, showing that 1 features two pentahapto bonded Cpbig ligands in a bent configuration with a Cpbig-GeCpbig angle of 161 degrees. Two out of ten benzyl substituents point towards the

  GeCpbig2 (1) [Cpbig = C5(CH2C6H4-iPr)5] 是通过 KCpbig 与 GeCl 溶液或 GeCl2 的反应合成的，得到无色晶体。1 的分子结构由 X 射线衍射确定，表明 1 具有两个五触键键合的 Cpbig 配体，其 Cpbig-GeCpbig 角为 161 度。十分之二的苄基取代基指向锗原子处的孤对电子对，使两个分子完美地结合在一起，从而在固态中形成 1 的二聚体排列。可以分离 1 的两个多晶型物，其中 1 的取向不同。正如量子化学计算表明的那样，所有苄基取代基都指向远离锗原子的开放结构仅受到 21.6 kJ 中心点 mol1 的不利影响。在开放式结构中，仍然实现了弯曲布置，
• Mass spectrometry of π-complexes of transition metals. XXIII. The ions [C5H5EIV]+ in the gas phase. Synthesis and structure
  作者：Yu.S. Nekrasov、V.F. Sizoi、D.V. Zagorevskii、Yu.A. Borisov

  DOI：10.1016/s0022-328x(00)81471-0

  日期：1981.2

  The ions C5HE+ (E = C, Si, Ge, Sn, Pb) were generated in the gas phase. Calculations of the atomization energies confirm their structure as nido-cluster. It is suggested that such ions could be synthesized under normal conditions for all the Group IVA elements, including carbon.

  在气相中生成离子C 5 HE +（E = C，Si，Ge，Sn，Pb）。雾化能量的计算证实了其结构为nido团簇。建议可以在正常条件下为包括碳在内的所有IVA族元素合成此类离子。
• {Ge₈[Fe(CO)₄]₈}⁷⁻: an anionic cubic germanium-iron-cluster featuring an unpaired electron
  作者：Lars Preißing、Claudio Schrenk、Andreas Schnepf

  DOI：10.1039/d2dt01090a

  日期：——

  The reaction of a metastable Ge(i)Cl solution and Na₂Fe₂(CO)₈ gives the radical cluster anion (thf)₁₄Na₆Ge₈[Fe(CO)₄]₈}⁻ which might be an intermediate compound on the formation of metalloid germanium clusters.

  态Ge(i)Cl溶液与Na2Fe2(CO)8反应产生了自由基团簇阴离子(thf)14Na6Ge8[Fe(CO)4]8}-，它可能是形成金属锗团簇的中间化合物。
• Nonradiative decay pathways of electronic states of group IV tetrafluoro and tetrachloro molecular ions studied with synchrotron radiation
  作者：J. C. Creasey、I. R. Lambert、R. P. Tuckett、K. Codling、L. J. Frasinski、P. A. Hatherly、M. Stankiewicz、D. M. P. Holland

  DOI：10.1063/1.458810

  日期：1990.9

  The nonradiative decay channels of the valence electronic states of the gas-phase tetrahedral ions CF+4, SiF+4, CCl+4, SiCl+4, and GeCl+4 have been studied in the range 35–100 nm by a novel form of photoionization mass spectrometry. Tunable vacuum UV radiation from a synchrotron source ionizes the parent neutral molecule, and electrons and ions are detected by the photoelectron–photoion coincidence technique. The experiment is repeated continuously as a function of photon energy, and a three-dimensional histogram of photon energy versus ion time of flight versus coincidence count rate is produced. By taking cuts through this histogram, photoionization curves for the different fragment ions can be extracted. The appearance energies of the fragment ions (e.g., CF+2 from CF4, CCl+ from CCl4) occur at the adiabatic ionization potential of an electronic state of the parent ion, and not at the thermodynamic appearance energy of that ion. Attempts to measure the kinetic-energy releases in the fragmentation pathways have only been partially successful. The results are complementary to those of recent experiments to probe the radiative decay of these electronic states of MX+4 [M=C, Si, Ge; X=F, Cl] [J. Chem. Phys. 89, 2675 (1988); 89, 2683 (1988)], where the C̃ 2T2 and D̃ 2A1 third and fourth excited electronic states can show radiative decay to a surprising degree. The decay dynamics of the C̃ and D̃ states of MX+4 are reviewed. In general, the fluorides show different behavior to the analogous chlorides, and the carbon species behaves differently to the corresponding silicon or germanium species.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ge: SVol., 112, page 513 - 516
  作者：

  DOI：——

  日期：——