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六水高氯酸铈 | 14017-47-1

中文名称
六水高氯酸铈
中文别名
高氯酸铈(III)盐六水合物;高氯酸铈盐六水合物
英文名称
cerium perchlorate
英文别名
Cerium(3+) perchlorate;cerium(3+);triperchlorate
六水高氯酸铈化学式
CAS
14017-47-1
化学式
CeCl3O12
mdl
——
分子量
438.472
InChiKey
LJBTWTBUIINKRU-UHFFFAOYSA-K
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 密度:
    1.501 g/mL at 25 °C
  • 稳定性/保质期:

    在常温常压下,该物质保持稳定。

    应避免与以下物料接触:还原剂、易氧化材料、属粉末和有机材料。此外,它具有吸湿性,并可溶于乙醇。在真空条件下,于200℃时会失

计算性质

  • 辛醇/水分配系数(LogP):
    -14.27
  • 重原子数:
    16
  • 可旋转键数:
    0
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    223
  • 氢给体数:
    0
  • 氢受体数:
    12

ADMET

毒理性
  • 副作用
血红蛋白血症 - 血液中高血红蛋白含量增加;该化合物被归类为继发性毒性效应。
Methemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect
来源:Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

安全信息

  • TSCA:
    Yes
  • 危险等级:
    5.1
  • 危险品标志:
    O,Xi
  • 安全说明:
    S17,S26,S36
  • 危险类别码:
    R8
  • 包装等级:
    II
  • 危险类别:
    5.1
  • 危险品运输编号:
    UN 3098 5.1/PG 2
  • 储存条件:
    请将产品存放在常温环境下,密闭避光且保持干燥通风。

SDS

SDS:babd02563308f6e1cdd3e6e0b16d991d
查看
Version 1.2
Regulation (EC) No 1907/2006

1 - Product and Company Information

Product Name CERIUM(III) PERCHLORATE, 99.5%, 40 WT.
% SOLUTION IN WATER

2 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Contact with combustible material may cause fire. Irritating to
eyes, respiratory system and skin.

3 - Composition/Information on Ingredients

Product Name CAS # EC no Annex I
Index Number
CERIUM(III) PERCHLORATE, 99.5%, 14017-47-1 237-836-2 None
40 WT. %SOLUTION IN WATER
Formula Ce(ClO4)3
Molecular Weight 438,4700 AMU

4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.

5 - Fire Fighting Measures

CONDITIONS OF FLAMMABILITY
May accelerate combustion.
EXTINGUISHING MEDIA
Suitable: Water spray.
SPECIAL RISKS
ALDRICH www.molbase.com
Specific Hazard(s): Emits toxic fumes under fire conditions. May
accelerate combustion. Contact with other material may cause
fire.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry lime or soda ash, pick up, keep in a closed
container, and hold for waste disposal. Ventilate area and wash
spill site after material pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Store in a cool dry
place.
Unsuitable: Do not store near, nor allow contact with, clothing
and other combustible material.

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before
reuse.
PERSONAL PROTECTIVE EQUIPMENT
Special Protective Measures: Wear appropriate government approved
respirator, chemical-resistant gloves, safety goggles, other
protective clothing.

9 - Physical and Chemical Properties

pH N/A
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
ALDRICH www.molbase.com
SG/Density 1,5010 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A

10 - Stability and Reactivity

STABILITY
Stable: Stable.
Materials to Avoid: Organic materials, Finely powdered metals,
Strong reducing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Chlorine.

11 - Toxicological Information

SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Rare earth compounds may cause delayed blood clotting leading to
hemorrhages. Inhalation of rare earths may cause sensitivity to
heat, itching, and increased awareness of odor and taste.
ROUTE OF EXPOSURE
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract.
Multiple Routes: May be harmful by inhalation, ingestion, or
skin absorption. Causes eye and skin irritation.

12 - Ecological Information

No data available.

13 - Disposal Considerations

SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Observe all federal, state, and local
environmental regulations.

14 - Transport Information

RID/ADR
UN#: 3098
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: Oxidizing liquid, corrosive,
n.o.s.
ALDRICH www.molbase.com
IMDG
UN#: 3098
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: OXIDIZING LIQUID, CORROSIVE,
N.O.S.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 3098
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: Oxidizing liquid, corrosive,
n.o.s.
Inhalation Packing Group I: No
Technical Name: Required

15 - Regulatory Information

CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: O-Xi
Oxidizing. Irritant.
R-PHRASES: 8-36/37/38
Contact with combustible material may cause fire. Irritating to
eyes, respiratory system and skin.
S-PHRASES: 17-26-36
Keep away from combustible material. In case of contact with
eyes, rinse immediately with plenty of water and seek medical
advice. Wear suitable protective clothing.

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
ALDRICH www.molbase.com


SECTION 16 - ADDITIONAL INFORMATION
N/A


制备方法与用途

生产方法: 计量的氧化铈(Ⅲ)用热的稀高氯酸溶液处理,随后过滤并使用旋转蒸发器在浴上将滤液浓缩至干燥。

反应信息

  • 作为反应物:
    描述:
    cesium perchlorate六水高氯酸铈高氯酸 为溶剂, 生成
    参考文献:
    名称:
    Skogareva, L. S.; Babaeva, V. P.; Rosolovskii, V. Ya., Russian Journal of Inorganic Chemistry, 1986, vol. 31, p. 500 - 503
    摘要:
    DOI:
  • 作为产物:
    描述:
    hydrated cerium perchlorate 以 neat (no solvent) 为溶剂, 生成 六水高氯酸铈
    参考文献:
    名称:
    Skogareva, L. S.; Babaeva, V. P.; Rosolovskii, V. Ya., Russian Journal of Inorganic Chemistry, 1986, vol. 31, p. 500 - 503
    摘要:
    DOI:
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