bismuth oxide

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属有机物
• 英文名称: bismuth oxide
• 英文别名: bismuthane;trihydrate
• 化学式: BiO₃
• 分子量: 256.979
• InChiKey: LNKLMRHKHWJLEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.66
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  bismuth oxide 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  Gattow, G.; Klippel, W., Zeitschrift für anorganische und allgemeine Chemie

  摘要：

  DOI：
• 作为产物：
  描述：

  bismuth (III) nitrate pentahydrate 以 乙醇 、 乙二醇 为溶剂， 反应 6.0h， 生成 bismuth oxide
  参考文献：
  名称：

  制备具有增强光催化降解四环素的二维/二维 Z 型高结晶氮化碳/δ-Bi2O3 异质结光催化剂

  摘要：

  光催化降解污染水中的抗生素污染物对环境保护至关重要。合理开发和设计具有高催化活性和稳定性的复合光催化剂在光催化领域具有重要作用。在此，二维/二维高结晶氮化碳/δ-Bi 2 O 3(HCCN/BO) Z 型异质结光催化剂是通过简便的溶剂热策略合成的。实验结果表明，最佳 HCCN/BO-3 样品在 60 分钟内光催化降解四环素 (TC) 的过程中表现出约 90% 的降解率。光催化活性的增强主要归因于以下两个原因：(i) 2D/2D异质结的形成缩短了载流子从体到表面的距离，并赋予了两种半导体丰富的活性位点，提高了产量光生活性载流子分离效率；(ii) 光生电子的传输路径遵循Z-scheme，可以有效抑制电子和空穴的复合，扩大宽带隙，收获更多的可见光，分离氧化和还原活性位点以保持氧化还原能力。最后，利用液相色谱-串联质谱法(LC-MS)确定了降解途径中的中间体，并提出了该复合体系光催化反应过程的TC降解途径。

  DOI：

  10.1016/j.jallcom.2021.162667

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Bi: SVol., 151, page 646 - 647
  作者：

  DOI：——

  日期：——
• Novel mixed method for the electrochemical deposition of thick layers of Bi2+xTe3−x with controlled stoichiometry
  作者：Wulf Glatz、Lukas Durrer、Etienne Schwyter、Christofer Hierold

  DOI：10.1016/j.electacta.2008.06.065

  日期：2008.12

  A new method for the electrochemical deposition of Bi2+xTe3-x is presented, which combines voltage-controlled deposition pulses with current-controlled resting pulses. This method is based on results of a comprehensive electrochemical investigation including cyclic voltammetry, chronoamperometry and chronopotentiometry, which has been performed on the system Bi and Te on Pt in 2 M HNO3. The influence of electrolyte composition, deposition potential and deposition pulse duration on morphology and stoichiometry of the deposited material as well as the variation of the composition over the thickness of the layer has been investigated by means of SEM and EDX. The crystal structure was examined with XRD. Layers deposited with the new method show a constant and reproducible stoichiometry over their entire thickness. Layers of up to 800 mu m thickness deposited with deposition rates of up to 50 mu m/h have been achieved. The composition and hence the thermoelectric behavior may be adjusted via electrolyte composition or the deposition potential. Fabrication of n-type and, for the first time, p-type Bi2+xTe3-x is demonstrated and verified by measurements of the Seebeck coefficients. The suitability of the proposed method for low-cost fabrication of micro-thermoelectric devices is shown. The advantages of this method may also apply for electrochemical deposition of other binary or ternary compounds. (C) 2008 Elsevier Ltd. All rights reserved.
• Modulation-free phase in heavily Pb-doped (Bi,Pb)2212 crystals
  作者：N. Musolino、S. Bals、G. van Tendeloo、N. Clayton、E. Walker、R. Flükiger

  DOI：10.1016/s0921-4534(03)01324-8

  日期：2003.11

  We report the complete disappearance of the structural modulation in heavily lead-doped Bi2-xPbxSr2CaCu2O8+delta crystals observed by transmission electron microscopy. Crystals with a nominal lead content of x = 0.8, corresponding to an effective lead content of x = 0.39, yield the non-modulated phase. The superconducting properties of this modulation-free phase (beta phase) have been studied and compared to those of undoped crystals displaying the modulated phase (alpha phase). Magnetisation measurements reveal that the irreversibility field H-irr(T) and relaxation rates are strongly improved within the beta phase. Measurements of the lower critical field, H-c1, show that the anisotropy factor, epsilon, is considerably reduced in the modulation-free crystals. This is the signature of stronger coupling between CuO2 layers which in turn deeply influences the effectiveness of the pinning. These measurements explain the enhanced pinning properties in moderately Pb-doped crystals in which the alpha phase and beta phase coexist. The enhanced pinning is not only due to the alpha/beta interfaces, which act as effective pinning centers: the emergence of modulation-free domains, characterized by a strongly reduced anisotropy, also significantly contribute to this effect. (C) 2003 Elsevier B.V. All rights reserved.
• Transport critical currents in Bi Sr Ca Cu O pellets and single crystals.
  作者：A. De Ninno、P. Gislon、M. Marinelli、G. Paterno'、U. Gambardella、P. Paroli、G. Balestrino

  DOI：10.1016/0921-4534(89)91054-x

  日期：1989.12
• Preparation of the 110 K high Tc superconductor Bi2Sr2Ca2Cu3Oy by Pb and Sb substitution
  作者：M. Pissas、D. Niarchos

  DOI：10.1016/0921-4534(89)91298-7

  日期：1989.7