chromium;cobalt;tetrahydrate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• 英文名称: chromium;cobalt;tetrahydrate
• 化学式: Co₂CrO₄
• 分子量: 233.98
• InChiKey: GAZGVYUAIZTQGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.31
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  氢气 、 chromium;cobalt;tetrahydrate 生成 钴
  参考文献：
  名称：

  Bracconi, P.; Dufour, L. C., Journal de Chimie Physique et de Physico-Chimie Biologique, 1991, vol. 88, # 4, p. 421 - 450

  摘要：

  DOI：
• 作为产物：
  描述：

  在 synthetic air 作用下， 以 neat (no solvent) 为溶剂， 生成 chromium;cobalt;tetrahydrate
  参考文献：
  名称：

  Thermal decomposition of homo- and heterometallic (η6-arene)tricarbonylchromium derivatives

  摘要：

  The thermal decomposition of homo- and heterometallic (eta(6)-arene)tricarbonylchromium complexes in dry air has been investigated by thermogravimetric analysis. The final decomposition products are characterized by X-ray powder diffractometry which confirms the formation of Cr2O3, PdO and Co2CrO4 (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0040-6031(99)00079-9
• 作为试剂：
  描述：

  (甲基硫代)醋酸乙酯 在 chromium;cobalt;tetrahydrate 、 双氧水 作用下， 以 水 、 叔丁醇 为溶剂， 反应 1.17h， 以96%的产率得到苯亚磺酰乙酸乙酯
  参考文献：
  名称：

  Synthesis, characterization and application of nano-sized Co2CrO4 spinel catalyst for selective oxidation of sulfides to sulfoxides

  摘要：

  The nano-sized Co2CrO4 spinel was produced for the first time by thermal decomposition of Cr-Co gel prepared by sol-gel method. It was shown that well-crystallized spinel structure is formed after calcination at 450 degrees C. The usual characterizations were performed and the results showed the particle size of the prepared spinel is 9 nm. Moreover, the prepared nano-sized Co2CrO4 spinel was applied in a simple, efficient and recyclable method for selective oxidation of sulfides to their corresponding sulfoxides with aqueous hydrogen peroxide in tert-butanol. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2011.10.029

文献信息

• Crystal structures and thermal behaviour of double complex compounds incorporating the [Cr{CO(NH2)2}6]3+ cation
  作者：S.I. Pechenyuk、А.А. Zolotarev、A.N. Gosteva、D.P. Domonov、А.А. Shimkin

  DOI：10.1016/j.molstruc.2017.06.099

  日期：2017.11

  Abstract Double complex compounds (DCC) of the [Cr(ur)6][Fe(CN)6]·4H2O (I), [Cr(ur)6][Co(CN)6]·4H2O (II), [Cr(ur)6][Fe(Ox)3]·2H2O (III), and [Cr(ur)6][Co(Ox)3].3.5H2O (IV) composition, where ur is CO(NH2)2, Ох – С2О42− have been synthesized and their crystal structures have been studied. The DCC I, II and IV are triclinic (Р-1); III is orthorhombic (С2221). The DCC thermal behavior in air and argon

  摘要 [Cr(ur)6][Fe(CN)6]·4H2O (I), [Cr(ur)6][Co(CN)6]·4H2O (II), [ Cr(ur)6][Fe(Ox)3]·2H2O (III)和[Cr(ur)6][Co(Ox)3].3.5H2O (IV)组成，其中ur为CO(NH2)2 , Ох – С2О42− 已被合成并研究了它们的晶体结构。DCC I、II 和 IV 是三斜晶系 (Р-1)；III 是正交晶系 (С2221)。通过以下参数分析空气和氩气气氛中的 DCC 热行为：完全分解的温度区间以及气态和固态产物的性质。空气中的最终固体产物是 FeO 和 FeCr2O4（I），CоCr2O4 + Со2CrO4 的混合物（II 和 IV）和 X 射线非晶相，其组成为 CrFeO2.5（III）。气态产物为 HCN、NH3、HNCO、N2O、СО、СО2、N2 和尿素。在空气中完全分解的温度为：I、II
• Hydrothermal synthesis and enhanced xylene-sensing properties of pompon-like Cr-doped Co₃O₄hierarchical nanostructures
  作者：Yujia Li、Xiaohui Ma、Sijia Guo、Bin Wang、Dongming Sun、Xindong Zhang、Shengping Ruan

  DOI：10.1039/c5ra26466a

  日期：——

  Unique pompon-like Cr-doped Co₃O₄hierarchical nanostructures were preparedviaa hydrothermal method, showing extraordinary sensing properties towards xylene.

  通过水热法制备了独特的掺铬 Co3O4 层状纳米结构，该结构对二甲苯具有非凡的传感性能。
• Thermolysis of [Co(NH3)6][Cr(C2O4)3]
  作者：S. I. Pechenyuk、D. P. Domonov、A. T. Belyaevskii

  DOI：10.1134/s0036023608080123

  日期：2008.8

  Thermolysis of the double-metal complex [Co(NH3)(6)][Cr(C2O4)(3)] was studied in air at 200, 350, and 500 degrees C and in a hydrogen atmosphere at 200, 350, 500, 700, and 900 C, as well as the composition and properties of thermolysis products. Oxidative thermolysis produces mixed oxides CoCr2O4 and Co2CrO4; reductive thermolysis produces Co+Cr2O3 mixture. Specific surface areas were measured for reductive thermolysis products; the maximal specific surface area and, therefore, maximal dispersion are reached at 500 degrees C. The morphology of the reductive thermolysis products and the thermolysis chemism were studied in relation to the nature of the complex anion.
• Synthesis, characterization and application of nano-sized Co2CrO4 spinel catalyst for selective oxidation of sulfides to sulfoxides
  作者：Mohammad Yazdanbakhsh、Iman Khosravi、Mahboobeh-Sadat Mashhoori、Mohammad Rahimizadeh、Ali Shiri、Mehdi Bakavoli

  DOI：10.1016/j.materresbull.2011.10.029

  日期：2012.2

  The nano-sized Co2CrO4 spinel was produced for the first time by thermal decomposition of Cr-Co gel prepared by sol-gel method. It was shown that well-crystallized spinel structure is formed after calcination at 450 degrees C. The usual characterizations were performed and the results showed the particle size of the prepared spinel is 9 nm. Moreover, the prepared nano-sized Co2CrO4 spinel was applied in a simple, efficient and recyclable method for selective oxidation of sulfides to their corresponding sulfoxides with aqueous hydrogen peroxide in tert-butanol. (C) 2011 Elsevier Ltd. All rights reserved.
• Bracconi, P.; Dufour, L. C., Journal de Chimie Physique et de Physico-Chimie Biologique, 1991, vol. 88, # 4, p. 421 - 450
  作者：Bracconi, P.、Dufour, L. C.

  DOI：——

  日期：——