aluminum sulfide

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属有机物
• 英文名称: aluminum sulfide
• 英文别名: aluminum(III) sulfide；sulfanylidene(sulfanylidenealumanylsulfanyl)alumane
• 化学式: Al₂S₃
• 分子量: 150.161
• InChiKey: ZPXDOGRYMSWBBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.18
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  aluminum sulfide 生成 硫化碱
  参考文献：
  名称：

  MORACHEVSKIJ, A. G.;KLEBANOV, E. B.;SHARIVKER, V. S.;DEMIDOV, A. I., RASPLAVY,(1989) N, S. 88-90

  摘要：

  DOI：
• 作为产物：
  描述：

  硫化氢 生成 aluminum sulfide
  参考文献：
  名称：

  KIMURA, EHTSUDZI;NISIYAMA, YUTAKA;TANAKA, MITIXIRO

  摘要：

  DOI：

文献信息

• Matrix isolation study of the reaction of trimethylaluminum with hydrogen sulfide and mercaptans: synthesis and spectra of molecular aluminum sulfide
  作者：Bruce S. Ault

  DOI：10.1021/j100052a014

  日期：1994.1

  The high-temperature pyrolytic reaction of (CH3)3Al with H2S followed by trapping into argon matrices at 14 K has led to the formation and isolation of molecular Al2S3. Identification was made based on band positions, lack of deuterium shift, the observation of CH3D when D2S was employed, and a poor spectral match to known aluminum sulfides and by analogy to the molecular species B2O3 and Al2O3. The spectra are suggestive of a V-shaped molecule, also similar to B2O3 and in contrast to the linear structure of Al2O3. Local density functional calculations were also carried out in support of the experimental work. Reaction of (CH3)3Al with methyl and ethyl mercaptan led to the formation of (CH3) 2AlSR (R = CH3, C2H5), probably in the known dimeric structure.
• MELLING, PETER J.;MUTSUDDY, BEEBHAS C.;SEKERCIOGLU, IBRAHIM
  作者：MELLING, PETER J.、MUTSUDDY, BEEBHAS C.、SEKERCIOGLU, IBRAHIM

  DOI：——

  日期：——
• AGAEV, A. S.;KULIEV, T. M., VOPR. ULUCHSH. USLOVIJ I BEZOPAS. TRUDA V NEFT. PROM-STI, M.,(1988) S. 35+
  作者：AGAEV, A. S.、KULIEV, T. M.

  DOI：——

  日期：——
• JOHNSON, C. E.;HICKEY, D. K.;HARRIS, D. C., BETTER CERAM. THROUGH CHEM. II: SYMP., PALO ALTO, CALIF., APR. 15-19, 198+
  作者：JOHNSON, C. E.、HICKEY, D. K.、HARRIS, D. C.

  DOI：——

  日期：——
• JOHNSON, CURTIS E.;HICKEY, DEBORAH K.;HARRIS, DANIEL C., PROC. SOC. PHOTO-OPT. INSTRUM. ENG., 683,(1986) 112-115
  作者：JOHNSON, CURTIS E.、HICKEY, DEBORAH K.、HARRIS, DANIEL C.

  DOI：——

  日期：——