Cadmium;mercury;sulfane

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• 英文名称: Cadmium;mercury;sulfane
• 化学式: CdHgS
• 分子量: 347.09
• InChiKey: QZRXPHLGEKVHRU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.11
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  cadmium mercury tetrathiocyanate 以 neat (no solvent) 为溶剂， 生成 硫酸镉盐(1:1)单水合物 、 mercury sulfide 、 Cadmium;mercury;sulfane
  参考文献：
  名称：

  Combined spectroscopic investigation on the thermal decomposition mechanism of CdHg(SCN)4

  摘要：

  The very useful second order nonlinear optical crystal material: cadmium mercury thiocyanate, CdHg(SCN)(4), was synthesized and purified by using a simple and highly-effective method. The thermal decomposition process of CdHg(SCN)(4) was studied by means of thermogravimetric analysis and differential thermal analysis in air. The factual thermal decomposition behavior encountered throughout the heat treatment was investigated by using an electric muffle furnace. The samples calcined at different temperatures were characterized by X-ray powder diffraction and infrared spectroscopy techniques. The intermediates were cadmium mercury thiocyanates and sulfides, cadmium normal and basic sulfates, and the final product was cadmium oxide. A possible chemical decomposition procedure has been put forward and a theoretical explanation has been provided based on the crystal structure.

  DOI：

  10.1134/s0036023611050263