氨基(化)钙 | 23321-74-6

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 中文名称: 氨基(化)钙
• 英文名称: calcium amide
• 英文别名: Calcium;azanide；calcium;azanide
• CAS: 23321-74-6
• 化学式: CaH₄N₂
• 分子量: 72.1232
• InChiKey: BWKDLDWUVLGWFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.05
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  氨基(化)钙 、 tantalum(V) nitride 在 N₂ 作用下， 生成 、
  参考文献：
  名称：

  The high temperature preparation and property measurements of CaTaN2: A ternary superconducting nitride

  摘要：

  Highly crystalline CaTaN2 was prepared by the reaction of Ca(NH2)(2) and Ta3N5 in a specially designed reaction vessel at high temperatures (> 1300 degrees C). Even when reaction conditions varied considerably, the samples were always contaminated by small amounts of Ca2TaN3, TaN, or TaN0.1. SQUID measurements obtained on a sample contaminated by Ca2TaN3 and a sample contaminated by TaN and TaN0.1 showed superconducting transitions at 9.6 K and 9.1 K, respectively. Resistivity measurements carried out on a sintered pellet of CaTaN2 contaminated by TaN0.1 showed a rho(300 K) = 0.0147 omega cm and weakly rising resistivity with lower temperatures, likely due to the random alignment of the polycrystalline grains.

  DOI：

  10.1016/s0022-3697(96)00066-2
• 作为产物：
  描述：

  氨 、 calcium 生成 氨基(化)钙
  参考文献：
  名称：

  The high temperature preparation and property measurements of CaTaN2: A ternary superconducting nitride

  摘要：

  Highly crystalline CaTaN2 was prepared by the reaction of Ca(NH2)(2) and Ta3N5 in a specially designed reaction vessel at high temperatures (> 1300 degrees C). Even when reaction conditions varied considerably, the samples were always contaminated by small amounts of Ca2TaN3, TaN, or TaN0.1. SQUID measurements obtained on a sample contaminated by Ca2TaN3 and a sample contaminated by TaN and TaN0.1 showed superconducting transitions at 9.6 K and 9.1 K, respectively. Resistivity measurements carried out on a sintered pellet of CaTaN2 contaminated by TaN0.1 showed a rho(300 K) = 0.0147 omega cm and weakly rising resistivity with lower temperatures, likely due to the random alignment of the polycrystalline grains.

  DOI：

  10.1016/s0022-3697(96)00066-2

文献信息

• Preparation of certain alkaline earth metal organometallic compounds
  申请人：Lithium Corporation of America

  公开号：US04555498A1

  公开（公告）日：1985-11-26

  Stable, hydrocarbon-soluble organobarium-, organocalcium-, and organostrontium-containing polymerization initiators are prepared by reacting certain calcium, barium or strontium alkoxides with organolithium, diorganomagnesium or triorganoaluminum compounds and combinations thereof. By way of illustration, the barium alkoxides soluble in hydrocarbon or chlorinated hydrocarbon solvents are prepared by reacting a suspension of barium amide in a hydrocarbon or a chlorinated hydrocarbon solvent with stoichiometric quantities of certain alcohols, alone or in the presence of chelating tertiary di- or polyamines. Alcohols suitable for the preparation of hydrocarbon- or chlorinated hydrocarbon-soluble barium alkoxides are C.sub.4 -C.sub.12 aliphatic and cycloaliphatic alcohols possessing alkyl branches at the one or two-positions, or mixtures of such alcohols. Other suitable alcohols are 2-alkoxy-1-alkanols and .gamma.-alkoxy-poly(ethyleneoxy)-1-ethanols.

  稳定的，亲油的有机钡、有机钙和有机锶聚合引发剂是通过将某些钙、钡或锶醇盐与有机锂、二元有机镁或三元有机铝化合物及其组合物反应制备而成。例如，可通过在烃或氯化烃溶剂中悬浮钡酰胺并与一定量的某些醇（单独或与螯合三级二元或多元胺一起）反应制备亲油的或氯化烃溶解的钡醇盐。用于制备亲油或氯化烃溶解的钡醇盐的醇包括在1-2位具有烷基支链的C.sub.4-C.sub.12脂肪族和环脂肪族醇，或这些醇的混合物。其他适用的醇包括2-烷氧基-1-烷醇和.gamma.-烷氧基-聚（乙二醇氧基）-1-乙醇。