Bis(N,N,N-trihexylhexan-1-aminium) sulfate | 111951-07-6

• 分子结构分类: 有机化合物 - 有机盐 - 有机硫酸盐
• 英文名称: Bis(N,N,N-trihexylhexan-1-aminium) sulfate
• 英文别名: tetrahexylazanium;sulfate
• CAS: 111951-07-6
• 化学式: C48H104N2O4S
• 分子量: 805.4
• InChiKey: KMXYYFRWQNNPDG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  14.91
• 重原子数：
  55
• 可旋转键数：
  40
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  88.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• ALICYCLIC EPOXY (METH)ACRYLATES, PROCESS FOR PRODUCTION THEREOF, AND COPOLYMERS
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1818327A1

  公开（公告）日：2007-08-15

  There are provided a novel compound having an 3,4-epoxytricyclo[5.2.1.02,6]decane skeleton and a polymerizable unsaturated bond, and a process for the preparation of the compound. There is also provided a copolymer including a monomeric unit (A) containing an alkali-soluble group, and a monomeric unit (B) corresponding to an epoxy-containing polymerizable unsaturated compound, or a copolymer including, in addition to the monomeric units (A) and (B), a monomeric unit (C) corresponding to an epoxy-free polymerizable unsaturated compound such as a N-substituted maleimide, in which the monomeric unit (B) occupies 40 to 90 percent by weight of total monomeric units, and 30 percent by weight or more of the monomeric unit (B) is a monomeric unit corresponding to a specific 3,4-epoxytricyclo[5.2.1.02,6]decane skeleton-containing compound. The copolymer can yield a film excellent typically in thermal stability, yield a resin composition having very high storage stability, and be easily synthetically prepared.

  提供了一种具有 3,4-环氧三环[5.2.1.02,6]癸烷骨架和可聚合不饱和键的新型化合物，以及制备该化合物的工艺。 还提供了一种共聚物，包括含有碱溶性基团的单体单元（A）和对应于含环氧可聚合不饱和化合物的单体单元（B），或一种共聚物，除单体单元（A）和（B）外，还包括对应于不含环氧的可聚合不饱和化合物（如 N-取代马来酰亚胺）的单体单元（C），其中单体单元（B）占总单体单元重量的 40%至 90%，单体单元（B）中 30%（重量）或更多是对应于特定 3,4-环氧三环[5.2.1.02,6]癸烷骨架化合物的单体单元。这种共聚物可以生成热稳定性极佳的薄膜，生成具有极高储存稳定性的树脂组合物，并且易于合成。
• METHOD FOR PRODUCING SILOXANE RESIN
  申请人：Kaneka Corporation

  公开号：EP3208295A1

  公开（公告）日：2017-08-23

  An object of the present invention is to rapidly produce condensates of various silane compounds containing different organic substituents by accelerating condensation reactions of the silane compounds containing hydrolyzable silyl groups without using acid or base catalysts. The present invention relates to a method for producing a siloxane resin, including: hydrolyzing and condensing a silane compound (B) containing a hydrolyzable silyl group represented by formula (I) below using a neutral salt (A) as a catalyst, the formula (I) being: RnSiX4-n wherein R represents an organic group having a carbon atom directly bonded to Si; X represents a hydroxyl group or a hydrolyzable group; and n represents an integer of 0-3, provided that when n is 2 or greater, each R may be the same as or different from each other, and when (4-n) is 2 or greater, each X may be the same as or different from each other.

  本发明的目的是在不使用酸或碱催化剂的情况下，通过加速含有可水解硅基的硅烷化合物的缩合反应，快速生产含有不同有机取代基的各种硅烷化合物的缩合物。本发明涉及一种生产硅氧烷树脂的方法，包括：使用中性盐（A）作为催化剂，水解和缩合含有下式（I）所代表的可水解硅基的硅烷化合物（B），式（I）为：RnSiX4-n 其中，R 代表具有与 Si 直接键合的碳原子的有机基团；X 代表羟基或可水解基团；n 代表 0-3 的整数，但当 n 为 2 或更大时，每个 R 可以相同或不同，当（4-n）为 2 或更大时，每个 X 可以相同或不同。
• PHOTOCURABLE AND THERMOSETTING RESIN COMPOSITION, CURED PRODUCT AND LAMINATE
  申请人：Kaneka Corporation

  公开号：EP3235845A1

  公开（公告）日：2017-10-25

  A condensation product having a high epoxy group residual ratio is obtained by accelerating, with use of neither an acid catalyst nor a base catalyst, hydrolysis and condensation reaction of a silyl group in a silane compound containing an epoxy structure-containing group. Then, a cured product is formed, which has high abrasion resistance, high chemical resistance and low cure shrinkage. The condensation product is synthesized from silane compounds at a specific ratio in the presence of a neutral salt catalyst, which silane compounds are represented by General Formula (I) and General Formula (II), respectively, and then cured with use of a curing agent which cures an epoxy group.

  在不使用酸催化剂也不使用碱催化剂的情况下，通过加速含有环氧结构基团的硅烷化合物中硅烷基的水解和缩合反应，可获得具有高环氧基残留率的缩合产品。然后形成一种固化产品，它具有高耐磨性、高耐化学性和低固化收缩率。缩合产物是在中性盐催化剂存在下，以特定比例从硅烷化合物中合成的，硅烷化合物分别由通式（I）和通式（II）表示，然后使用固化剂固化环氧基团。
• Method for producing siloxane resin
  申请人：Kaneka Corporation

  公开号：US10040907B2

  公开（公告）日：2018-08-07

  A method for producing a siloxane resin, by hydrolyzing and condensing a silane compound containing a hydrolyzable silyl group represented by RnSiX4-n using a neutral salt as a catalyst. In the formula RnSiX4-n, R represents an organic group having a carbon atom directly bonded to Si, X represents a hydroxyl group or a hydrolyzable group, and n represents an integer of 0 to 3, provided that when n is 2 or greater each R may be the same as or different from each other, and when (4-n) is 2 or greater, each X may be the same as or different from each other.

  一种生产硅氧烷树脂的方法，使用一种中性盐作为催化剂，通过水解和缩合含有 RnSiX4-n 所代表的可水解硅基的硅烷化合物。在式 RnSiX4-n 中，R 代表具有与 Si 直接键合的碳原子的有机基团，X 代表羟基或可水解基团，n 代表 0 至 3 的整数，条件是当 n 为 2 或更大时，每个 R 可以相同或不同，而当 (4-n) 为 2 或更大时，每个 X 可以相同或不同。
• Photocurable and thermosetting resin composition, cured product, and laminate
  申请人：Kaneka Corporation

  公开号：US10563088B2

  公开（公告）日：2020-02-18

  A curable composition includes a condensation product having a weight average molecular weight of 30,000 or less and a curing agent, the condensation product being obtained by hydrolysis and condensation of a first and second silane compound in the presence of a neutral salt catalyst. The condensation product also has a ratio Y/X of 0.2 or less, wherein X is the number of moles of an OR3 group directly bonded to silicon atoms of the first and second silane compounds, and Y is the number of moles of an OR3 group directly bonded to a silicon atom of the condensation product. The first silane compound is represented by R1—(SiR2a(OR3)3-a), and the second silane compound is represented by R4—(SiR2a(OR3)3-a).

  一种可固化组合物包括一种重量平均分子量为 30,000 或更小的缩合产物和一种固化剂，该缩合产物是由第一和第二硅烷化合物在中性盐催化剂存在下水解和缩合得到的。缩合产物的比率 Y/X 也为 0.2 或以下，其中 X 是直接键合到第一和第二硅烷化合物硅原子上的 OR3 基团的摩尔数，Y 是直接键合到缩合产物硅原子上的 OR3 基团的摩尔数。第一硅烷化合物用 R1-(SiR2a(OR3)3-a)表示，第二硅烷化合物用 R4-(SiR2a(OR3)3-a)表示。