Palladium--samarium (3/1) | 12165-88-7

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间过渡金属化合物
• 英文名称: Palladium--samarium (3/1)
• 英文别名: palladium;samarium
• CAS: 12165-88-7
• 化学式: Pd₃Sm
• 分子量: 469.62
• InChiKey: NGSOUCCMGAGEEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三氢化钐 、 钯 以 neat (no solvent) 为溶剂， 生成 Palladium--samarium (3/1)
  参考文献：
  名称：

  Valence States of Rare-Earth Ions in RERuSn3 (RE=La, Ce, Pr, Nd, Sm) and Related Compounds Studied by Core-Level Photoemission Spectroscopy

  摘要：

  We have measured the 3d and 4d core-level X-ray photoelectron spectra of rare earths in RERuSn3 (RE = La, Ce, Pr, Nd and Sm) and related rare-earth compounds. The Ce 3d spectra of CeRuSn(x) (x= 2.85, 3.0 and 3.15) show the common features observed in other cerium compounds. In the spectra, f0 structures cannot be apparently distinguished from other prominent structures f1 and f2 peaks, and broad structures are observed at the high binding energy side of the f1 peak. For SmRuSn3, both Sm 3d and 4d spectra show strong Sm'' components and the Sm valency is estimated to be 2.95 +/- 0.02.

  DOI：

  10.1143/jpsj.62.811

文献信息

• Valence States of Rare-Earth Ions in RERuSn3 (RE=La, Ce, Pr, Nd, Sm) and Related Compounds Studied by Core-Level Photoemission Spectroscopy
  作者：Hiroyoshi Ishii、Takaaki Hanyu、Tadashi Fukuhara、Isao Sakamoto、Hideyuki Sato、Shigeo Yamaguchi

  DOI：10.1143/jpsj.62.811

  日期：1993.2.15

  We have measured the 3d and 4d core-level X-ray photoelectron spectra of rare earths in RERuSn3 (RE = La, Ce, Pr, Nd and Sm) and related rare-earth compounds. The Ce 3d spectra of CeRuSn(x) (x= 2.85, 3.0 and 3.15) show the common features observed in other cerium compounds. In the spectra, f0 structures cannot be apparently distinguished from other prominent structures f1 and f2 peaks, and broad structures are observed at the high binding energy side of the f1 peak. For SmRuSn3, both Sm 3d and 4d spectra show strong Sm'' components and the Sm valency is estimated to be 2.95 +/- 0.02.