Einecs 234-622-0 | 12017-61-7

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间过渡金属化合物
• 英文名称: Einecs 234-622-0
• 英文别名: cobalt;gadolinium
• CAS: 12017-61-7
• 化学式: Co₅Gd
• 分子量: 452.216
• InChiKey: PPYDGEQIESHWIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Einecs 234-622-0 、 氢气 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Influence of magnetic fields on the equilibrium hydrogen pressures of ferromagnetic hydrides

  摘要：

  DOI：

  10.1016/0022-5088(91)90435-7
• 作为产物：
  描述：

  氢化钆 、 钴 以 melt 为溶剂， 生成 Einecs 234-622-0
  参考文献：
  名称：

  高温直接合成量热法生成某些镧系元素-钴二元合金的标准焓

  摘要：

  摘要 通过高温直接合成量热法在 1373 ± 2 K 下测量了某些镧系元素-钴系金属间化合物的标准形成焓。 报告了以下结果，单位为 kJ/mol 原子：CeCo 5 (-9.4 ± 3.3) ; Ce 2 Co 17 (-6.8 ± 3.2)；PrCo 5 (-10.5 ± 2.4)；Pr 2 Co 17 (-6.8 ± 3.6)；NdCo 5 (-12.7 ± 2.6)；Nd 2 Co 17 (-6.6 ± 2.7)；钐钴 5 (-12.2 ± 1.8)；Sm 2 Co 17 (-7.2 ± 2.5)；GdCo 5 (-10.0 ± 2.4)；Tb 2 Co 17 (-7.7 ± 2.9)；Dy 2 Co 17 (-8.1 ± 2.9)；HoCo 3 (-17.5 ± 2.2)；ErCo 3 (-19.7 ± 3.3)；TmCo 3 (-22.9 ± 3.0)；LuCo 3 (-23.0

  DOI：

  10.1016/j.jallcom.2013.05.162

文献信息

• 10.1016/0304-8853(83)90224-x
  作者：Yamaguchi、Ohta、Katayama

  DOI：10.1016/0304-8853(83)90224-x

  日期：——

  Abstract The magnetization of hydrides based on GdCo 5 and YCo 5 has been investigated as a function of hydrogen composition and temperature between 4.2 and 400 K under the direct influence of hydrogen. Hydrogen absorption leads to a reduction in the Co moment and weakenings in the Co-Co and the Co-Gd exchange interactions.

  摘要 在氢气的直接影响下，研究了基于 GdCo 5 和 YCo 5 的氢化物的磁化强度与氢成分和 4.2 至 400 K 之间的温度的函数关系。氢吸收导致 Co 矩的降低和 Co-Co 和 Co-Gd 交换相互作用的减弱。
• Thermoreversible permanent magnets in the quasibinary GdCo5−xCux system
  作者：R. M. Grechishkin、M. S. Kustov、O. Cugat、J. Delamare、G. Poulin、D. Mavrudieva、N. M. Dempsey

  DOI：10.1063/1.2347282

  日期：2006.9.18

  Ferrimagnetic GdCo5−xCux alloys exhibiting the effect of Gd- and 3d-sublattice magnetization compensations at defined temperatures were studied with respect to their use as thermoreversible permanent magnets (PMs). Coercive fields μ0Hc in the range of 0.3–1.6T were measured for annealed single crystals with x=1–2.2 having compensation points in the vicinity of room temperature. Two applications of

  研究了在限定温度下表现出 Gd 和 3d 亚晶格磁化补偿效果的亚铁磁性 GdCo5-xCux 合金作为热可逆永磁体 (PM) 的用途。对于在室温附近具有补偿点的 x=1-2.2 的退火单晶，测量了 0.3-1.6T 范围内的矫顽场 μ0Hc。展示了这种热可逆 PM 的两种应用，即热控致动器和非接触式温度传感器。
• Yermakov, Physics of Metals and Metallography, 1991, vol. 72, # 5, p. 1 - 39
  作者：Yermakov

  DOI：——

  日期：——
• Thermal expansion and spontaneous magnetostriction of RCo5 intermetallic compounds
  作者：A.V. Andreev、S.M. Zadvorkin

  DOI：10.1016/0921-4526(91)90011-3

  日期：1991.7

  Thermal expansion of RCo5 compounds (R = Pr, Nd, Sm, Gd, Tb, Dy, Ho) is investigated by X-ray diffractometry on single crystalline samples in the temperature range 5-1300 K. All compounds undergo large spontaneous magnetostrictive deformations, the volume effect reaches 3.2 x 10(-2) at 5 K in HoCo5.5. The contributions to the volume effect from Co-Co and R-Co exchange interactions are determined by comparison with YCo5, Y being the nonmagnetic analogue of R.
• Solid-state phase equilibria in the Gd–Co–Al ternary system at 1173K
  作者：Bo Zhou、Zhengfei Gu、Junqin Li、Gang Cheng、Jun Cheng、Chengfu Xu、Lei Ma

  DOI：10.1016/j.jallcom.2006.04.061

  日期：2007.3

  A portion of the isothermal section (1173 K) of the phase diagram of the Gd-Co-Al ternary system (up to 33.3 at.% Gd) were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersion spectroscopy (EDS) techniques. Fourteen single-phase regions (including solid solution regions of the binary compounds), twenty-five two-phase regions and twelve three-phase regions were found to exist at this isothermal section. In the GdCo2-GdAl2 system, the existence of the GdCo0.74Al1.26 phase is identified and it has a composition range of 30-45 at.% Al, the maximum solid solubility of Al in GdCo, is about 15 at.%, and Co in GdAl2, is about 16 at.%. Besides, the maximum solid solubility of Al in Co, Gd2Co17 and GdCo5 is about 6, 17 and 25 at.%, respectively, the maximum solid solubility of Gd in Co, CoAl is below 2 at.% and the solid solubility range is from 47 to 61 at.% Al in CoAl phase. In this work, no new ternary compounds were observed. (c) 2006 Elsevier B.V. All rights reserved.