| 1430412-65-9

• CAS: 1430412-65-9
• 化学式: CH₄O*C₁₈H₂₂N₆O₈Tb*NO₃
• 分子量: 703.381
• InChiKey: RTQCMFBPKUZGDJ-BWXMDPMSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 吡啶-2-甲醛 、 terbium(III) nitrate hexahydrate 、 1,8-二氨基-3,6-二氧杂辛烷 以 甲醇 为溶剂， 反应 3.08h， 以65%的产率得到
  参考文献：
  名称：

  Subcomponent Self-Assembly of Rare-Earth Single-Molecule Magnets

  摘要：

  A family of lanthanide complexes has been synthesized by the subcomponent self-assembly methodology. Molecular architectures, which were stable in solution and under ambient conditions, were designed by the in situ formation of ligands around lanthanide ion templates Magnetic studies indicated that, despite the low C-2 symmetry, 1 and 2 display single molecule magnet (SMM) behavior, with 1 exhibiting an effective energy barrier of the relaxation of the magnetization U-eff/k(B) = 50 K and the pre-exponential factor tau(o) = 6.80 X 10(-7) s. Step-like features in the hysteresis loops indicate the presence of quantum tunneling of the magnetization (QTM).

  DOI：

  10.1021/ic400098c