{platinum(μ-Cl)Cl(PhCHCH2)}2 | 60018-53-3

• 英文名称: {platinum(μ-Cl)Cl(PhCHCH2)}2
• 英文别名: sym-trans-{Pt(μ-Cl)Cl(PhCH=CH2)}2
• CAS: 60018-53-3
• 化学式: C₁₆H₁₆Cl₄Pt₂
• 分子量: 740.275
• InChiKey: NYFTUYGCARTJPG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {platinum(μ-Cl)Cl(PhCHCH2)}2 在 丙酮 作用下， 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Caseri; Pregosin, Organometallics, 1988, vol. 7, # 6, p. 1373 - 1380

  摘要：

  DOI：
• 作为产物：
  描述：

  cis-dichlorobis(styrene)platinum(II) 以 氯仿 为溶剂， 以93%的产率得到{platinum(μ-Cl)Cl(PhCHCH2)}2
  参考文献：
  名称：

  与铂配合物进行氢化硅烷化。新型双烯烃催化剂顺式-PtCl2（PhCH：CH2）2的制备，低温NMR光谱和X射线晶体结构

  摘要：

  DOI：

  10.1021/om00147a017

文献信息

• Photoinduced reactions of PtCl₆^2–with saturated hydrocarbons and other C–H containing compounds
  作者：Georgiy B. Shul'pin、Galina V. Nizova、Alexander E. Shilov

  DOI：10.1039/c39830000671

  日期：——

  Light irradiation of a solution of PtCl62– and an n-alkane (hexane or heptane) in MeCO2H or CF3CO2H–H2O yields the corresponding π-olefin complex of PtII, the formation of which is assumed to proceed via a σ-alkyl complex of PtIV; the reaction with acetone, which has no β-hydrogen atoms affords a stable σ-acetonyl complex of PtIV and σ-aryl complexes are formed on irradiation of PtCl62– with arenes.

  将 PtCl62â 和正烷烃（己烷或庚烷）在 MeCO2H 或 CF3CO2HâH2O 中的溶液进行光照射，可得到相应的 PtII Ï-烯烃络合物，假定该络合物的形成是通过 PtIV 的 Ï-烷基络合物进行的；与丙酮（丙酮中没有δ-氢原子）反应，可得到稳定的 PtIV Ï-丙酮络合物，而 PtCl62â 与烷烃进行照射，可形成 Ï-芳基络合物。
• Complexation of Unsaturated Carbon−Carbon Bonds in π-Conjugated Polymers with Transition Metals
  作者：Christian Huber、Felix Bangerter、Walter R. Caseri、Christoph Weder

  DOI：10.1021/ja003727w

  日期：2001.5.1

  The present paper explores the possibility of preparing pi-conjugated organometallic polymer hybrid systems based on a poly(p-phenylene ethynylene) (PPE) derivative, in which the ethynylene moieties of the polymer are coordinated to platinum(II) centers. The use of the "bifunctional" [Pt-(mu-Cl)Cl(PhCH=CH(2))](2) (2) allows, under appropriate conditions, the formation of three-dimensionally cross-linked

  本论文探讨了制备基于聚（对亚苯基乙炔）（PPE）衍生物的π共轭有机金属聚合物杂化系统的可能性，其中聚合物的乙炔部分与铂（II）中心配位。“双功能”[Pt-(mu-Cl)Cl(PhCH=CH(2))](2) (2) 的使用允许在适当条件下形成三维交联的共轭 PPE-铂（II）网络。[Pt-(mu-Cl)Cl(PhC(triple bond)CPh)](2) 作为模型化合物的合成以及 2 与二苯乙炔 (3) 的一系列模型反应使核磁共振研究成为可能揭示了许多平衡，并建议混合 Pt-苯乙烯-乙炔配合物作为关键结构。正如预期的那样，Pt 的配位显着影响 PPE 的光物理特性。
• Synthesis and characterization of some olefin/phosphine-tert-amine N-oxide platinum(II) complexes
  作者：Talal A.K. L-Allaf、Abdul-Hussain Khuthier、Hatham J. Abdul-Gani

  DOI：10.1016/s0020-1693(00)84370-4

  日期：1987.10

  Eighteen olefin (or tert-phosphine)-tert-amine N-oxide platinum(II) complexes of the general formula trans-[PtL(tert-amine N-oxide)Cl2] have been prepared, where L is ethylene, styrene, or triethylphosphine. The tert-amine N-oxides used in the complexation were of the N-aryl saturated heterocyclic type substituted at the ortho- or para-position with an electron withdrawal group, i.e. NO2, CN, COCH3

  已经制备了十八种通式为反式-[PtL（叔胺N-氧化物）Cl 2 ]的烯烃（或叔膦）-叔胺N-氧化物铂（II）配合物，其中L为乙烯，苯乙烯，或三乙基膦。用于络合的叔胺N-氧化物是在邻位或对位被电子撤离基团（即NO 2，CN，COCH 3，COC 6 H 5和）取代的N-芳基饱和杂环类型。COOC 2 ħ 5。通过元素分析，IR和1 H NMR光谱对复合物进行表征。
• Gel'man, A. D., Izvestia Sektora platiny i drugih blagorodnyh metallov., 1939, vol. 16, p. 21 - 28
  作者：Gel'man, A. D.

  DOI：——

  日期：——
• Trigonal-bipyramidal five-coordinate trisolefin complexes of platinum(II)
  作者：Larry Mink、Michael F. Rettig、Richard M. Wing

  DOI：10.1021/ja00006a028

  日期：1991.3

  Five-coordinate trigonal-bipyramidal platinum(II) becomes the ground-state geometry in the presence of the chelating diolefin 3,7-dimethylenebicyclo[3.3.1]nonane [DMBN]. Anionic sigma-donors invariably take up the axial positions, and the third trigonal position is generally held by a pi-donor-acceptor. These trigonal-bipyramidal complexes are inert to addition at the platinum center, but will react by dissociation of the third trigonal ligand. As long as the dissociative pathway is prohibited (e.g. by addition of excess olefin) the complexes are quite stable, and in particular do not react via. sigma-group migration to coordinated olefin. The prototypic complex [(C2H4)(DMBN)PtIICl2] crystallizes in the space group P2(1)/c,a = 7.629 (1) angstrom, b = 12.431 (1) angstrom, c = 14.714 (2) angstrom, and beta = 100.88 (1)-degrees. The trigonal-bipyramidal structure has C2-nu geometry with the 2-fold axis passing through the Pt atom and ethylene midpoint. The mirrors are respectively parallel and perpendicular to the trigonal plane. A final R factor of 2.6% was obtained based on 3126 3-sigma reflections observed of 3990 unique reflections collected at -79-degrees-C. Replacement of one axial chloride by a methyl group greatly enriches the NMR spectra due to removal of the 2-fold axis and one mirror and allows for detailed analysis of the solution structure as well as for the observation of dynamic process(es) related to ethylene dissociation.