1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde | 904690-32-0

• 英文名称: 1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde
• 英文别名: 1-carboxy-1'-(diphenylthiophosphanyl)ferrocene
• CAS: 904690-32-0
• 化学式: C₂₃H₁₉FeOPS
• 分子量: 430.29
• InChiKey: CRFPPEQBWXGUQL-UHFFFAOYSA-N

计算性质

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• sp3杂化的碳原子比例：
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反应信息

• 作为反应物：
  描述：

  1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde 、 sodium tetrahydroborate 在 sodium hydroxide 作用下， 以 甲苯 为溶剂， 以88%的产率得到[1'-(diphenylthiophosphanyl)ferrocen-1-yl]methanol
  参考文献：
  名称：

  New (1‐Phosphanylferrocen‐1′‐ and ‐2‐yl)methyl‐Linked Diaminocarbene Ligands: Synthesis and Rhodium(I) Complexes

  摘要：

  AbstractTwo ferrocenylmethanols, [1′‐(diphenylthiophosphanyl)ferrocen‐1‐yl]methanol (3) and [2‐(diphenylthiophosphanyl)ferrocen‐1‐yl]methanol (6), have been converted in one step into the 1,1′‐ and 1,2‐ferrocenediyl‐linked thiophosphane/N‐R‐imidazolium salts 4a,b and 7a,b (a: R = Me; b: R = 2,4,6‐Me3C6H2 or Mes). This straightforward method allows the linkage of an imidazolium group to a ferrocene unit with a nonsubstituted methylene bridge. After desulfurisation of the phosphane group, the ligands reacted with an RhI precursor, in the presence of tBuOK, to give cationic complexes 9a,b and 10a,b. All compounds were characterised by elemental analysis, NMR spectroscopy and mass spectrometry. The molecular structures of compounds 4a, 7a and 9a were determined by X‐ray crystallography. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

  DOI：

  10.1002/ejic.200601193
• 作为产物：
  描述：

  1,2,3,4,5,6,7,8-八硫杂环辛烷 、 1′-(diphenylphosphino)ferrocene-1-carbaldehyde 以 甲苯 为溶剂， 以89%的产率得到1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde
  参考文献：
  名称：

  Synthesis of [1′-(diphenylthiophosphoryl)ferrocenyl]ethyne and alkyne-metal complexes thereof

  摘要：

  The novel functionalized ferrocene, alkyne Ph2P(S)fcC CH (1; fc = ferrocene-1,1'-diyl) was synthesized from Ph2P(S)fcCHO (6) via the Corey-Fuchs reaction. It was further reacted with K-2[HgI4]KOH to give mercury(II) acetylide Hg{C CfcP(S)Ph-2}(2) (8), and with [Co-2(CO)(8)] to afford the trimetallic CO2Fe complex [(mu-eta(2): eta(2)-1){Co(CO)(3)}(2)](Co-Co) (9). All compounds were characterized by spectral methods (IR, NMR, and MS) and by combustion or high-resolution MS elemental analyses. In addition, the crystal structures of 1, Ph(2)PfcBr (5), 6, Ph2P(S)fcCH=CBr2 (7), and 9 were determined by single-crystal X-ray diffraction. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.02.027