bis(4-acetyloxime-3-methyl-1-phenyl-2-pyrazoline-5-ono)bis(3-methyl-1-phenyl-2-pyrazoline-5-one)nickel(II) | 592532-32-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮卓类
• 英文名称: bis(4-acetyloxime-3-methyl-1-phenyl-2-pyrazoline-5-ono)bis(3-methyl-1-phenyl-2-pyrazoline-5-one)nickel(II)
• CAS: 592532-32-6
• 化学式: C₄₄H₄₄N₁₀NiO₆
• 分子量: 867.587
• InChiKey: KHWPZOSOKFHWEA-MNDNPDPASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 4-acetyloxime-3-methyl-1-phenyl-2-pyrazoline-5-one 、 依达拉奉 以 乙醇 、 水 为溶剂， 以55%的产率得到bis(4-acetyloxime-3-methyl-1-phenyl-2-pyrazoline-5-ono)bis(3-methyl-1-phenyl-2-pyrazoline-5-one)nickel(II)
  参考文献：
  名称：

  Synthesis, Magnetic, and Spectral Studies of Mixed‐Ligand Complexes of Nickel(II) Involving Some Chelating 4‐Oximino‐2‐pyrazoline‐5‐one Derivatives

  摘要：

  The synthesis, magnetic and spectral studies of mixed-ligand complexes of nickel(II) derived from chelating 4-oximino-2-pyrazoline-5-one derivatives, viz., 4-benzoyloxime-3-methyl-1-phenyl-2-pyrazoline-5-one (bomppH), 4-acetyloxime-3-methyl-1-phenyl-2-pyrazoline-5-one (aomppH) and 3-methyl-1-phenyl-4-propionyloxime-2-pyrazoline-5-one (mppopH), and certain heterocyclic ligands, viz., 3-methyl-1-phenyl-2-pyrazoline-5-one (mpp), 4-amino-2,3-dimethyl-1-phenyl-3-pyrazoline-5-one (adpp), 2,3-dimethyl-1-phenyl-3-pyrazoline-5-one (dpp), 2,3-dimethyl-4-methylaminomethanesulfonate sodium-1-phenyl-3-pyrazoline-5-one (dmspp), benzimidazole (bzl) and benzothiazole (bzt) are described. The complexes, which have been characterized by conducts ance measurements, electron spin resonance, magnetic measurements, thermogravimetric analyses, electronic and infrared spectral studies have the general formulas [Ni(A-A)(2)(L)(2)] and [Ni(A-A)(2)(L-L)] where, (A-A)H = bomppH, aomppH, or mppopH, L = mpp, dpp, bzl or bzt and L - L = adpp or dmspp. All the complexes were found to be non-electrolytes and octahedral structures have been proposed for them.

  DOI：

  10.1081/sim-120019997