K[B(iPr-4-Br-pyz)4] | 1310069-73-8

• 英文名称: K[B(iPr-4-Br-pyz)4]
• 英文别名: K[B(3-isopropyl-4-bromopyrazolatei)4]
• CAS: 1310069-73-8
• 化学式: C₂₄H₃₂BBr₄N₈*K
• 分子量: 802.097
• InChiKey: YODHWNYDKROEGX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  cobalt(II) nitrate hexahydrate 、 K[B(iPr-4-Br-pyz)4] 在 KCl 作用下， 以 四氢呋喃 、 甲醇 、 水 为溶剂， 以42%的产率得到[Co((μ-3-isopropyl-4-bromopyrazolate)2B(3-isopropyl-4-bromopyrazolate)2-κ2N)2]
  参考文献：
  名称：

  Use of pyrazolyl ligands for the formation of a bimetallic cobalt–ruthenium complex

  摘要：

  A straightforward route to Ru(pyz)(2)(Hpyz)(4) (Hpyz = pyrazole) has been developed. This has been found to react readily with a modified Co(pyrazolylborate)Cl complex in the presence of triethylamine as an HCl acceptor to yield a bimetallic cobalt-ruthenium complex, in which the two metals are each six-coordinate, and bridged by three pyrazolyl anions. Both species have been characterized structurally, as has a modified Co(pyrazolylborate)(2) complex. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.04.023
• 作为产物：
  描述：

  3-甲基-2-丁酮 在 钾硼氢 、 溴 、 sodium methylate 作用下， 以 水 、 甲苯 为溶剂， 反应 18.58h， 生成 K[B(iPr-4-Br-pyz)4]
  参考文献：
  名称：

  Use of pyrazolyl ligands for the formation of a bimetallic cobalt–ruthenium complex

  摘要：

  A straightforward route to Ru(pyz)(2)(Hpyz)(4) (Hpyz = pyrazole) has been developed. This has been found to react readily with a modified Co(pyrazolylborate)Cl complex in the presence of triethylamine as an HCl acceptor to yield a bimetallic cobalt-ruthenium complex, in which the two metals are each six-coordinate, and bridged by three pyrazolyl anions. Both species have been characterized structurally, as has a modified Co(pyrazolylborate)(2) complex. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.04.023