[Ir(I)(salicylidenebenzyliminato)(1,5-cyclooctadiene)] | 953087-76-8

• 英文名称: [Ir(I)(salicylidenebenzyliminato)(1,5-cyclooctadiene)]
• CAS: 953087-76-8
• 化学式: C₂₂H₂₄IrNO
• 分子量: 510.659
• InChiKey: GJXILSICBRKMND-QDZRWOFASA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ir(I)(salicylidenebenzyliminato)(1,5-cyclooctadiene)] 、 四-2-吡啶基吡嗪 以 二氯甲烷 为溶剂， 以75%的产率得到[Ir(I)(salicylidenebenzyliminato)(1,5-cyclooctadiene)(tetra-2-pyridinylpyrazine)]
  参考文献：
  名称：

  Iridium(I)-salicylaldiminato-cyclooctadiene complexes used as catalysts for phenylborylation

  摘要：

  Iridium(I) salicylaldiminato-cyclooctadiene complexes, Ir(-o-O-C6H4-CH=N-R)(cod) (R = CH2Ph (1), Ph (2); cod = 1,5-cyclooctadiene), have been prepared, characterized and used as catalysts for arylborylation via C-H activation. With 1 as a catalyst, isolated yields of up to 91% has been achieved for the borylation of benzene by bis(pinacolato)diboron in the presence of tetra-2-pyridinylpyrazine and an ionic liquid. The catalytic system could be recycled for at least three times without loss of activity. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.06.052
• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)diiridium(I) dichloride 、 诺来替酚 在 sodium hydride 作用下， 以 四氢呋喃 、 乙醚 、 mineral oil 为溶剂， 以82%的产率得到[Ir(I)(salicylidenebenzyliminato)(1,5-cyclooctadiene)]
  参考文献：
  名称：

  Iridium(I)-salicylaldiminato-cyclooctadiene complexes used as catalysts for phenylborylation

  摘要：

  Iridium(I) salicylaldiminato-cyclooctadiene complexes, Ir(-o-O-C6H4-CH=N-R)(cod) (R = CH2Ph (1), Ph (2); cod = 1,5-cyclooctadiene), have been prepared, characterized and used as catalysts for arylborylation via C-H activation. With 1 as a catalyst, isolated yields of up to 91% has been achieved for the borylation of benzene by bis(pinacolato)diboron in the presence of tetra-2-pyridinylpyrazine and an ionic liquid. The catalytic system could be recycled for at least three times without loss of activity. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.06.052
• 作为试剂：
  描述：

  甲苯 、 联硼酸频那醇酯 在 [Ir(I)(salicylidenebenzyliminato)(1,5-cyclooctadiene)] tetra-2-pyridinylpyrazine 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 生成 3-甲基苯硼酸 、 4-甲苯硼酸
  参考文献：
  名称：

  Iridium(I)-salicylaldiminato-cyclooctadiene complexes used as catalysts for phenylborylation

  摘要：

  Iridium(I) salicylaldiminato-cyclooctadiene complexes, Ir(-o-O-C6H4-CH=N-R)(cod) (R = CH2Ph (1), Ph (2); cod = 1,5-cyclooctadiene), have been prepared, characterized and used as catalysts for arylborylation via C-H activation. With 1 as a catalyst, isolated yields of up to 91% has been achieved for the borylation of benzene by bis(pinacolato)diboron in the presence of tetra-2-pyridinylpyrazine and an ionic liquid. The catalytic system could be recycled for at least three times without loss of activity. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.06.052