摘要:
Oxidative decarbonylation of Mn2(CO)10 by amine oxide in the presence of phosphites P(OR)3 (R = Me, Et, Ph, CH2CF3, CH2CH2Cl) led to good yields of Mn2(CO)9[P(OR)3]. Coordination of the phosphite and its influence of the manganese centres have been studied by P(2p) and Mn(2p) X-ray photoelectron spectroscopy.