| 202283-35-0

• CAS: 202283-35-0
• 化学式: C₆H₁₅N*C₁₄H₇Fe₂O₇S*H
• 分子量: 533.165
• InChiKey: ZDIGWFGTBOUNOJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二硫化碳 、 以 四氢呋喃 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  （二膦）镍桥双蝶Fe / S团簇配合物的合成及反应性含μ-CO的阴离子Fe / S团簇中间体的分离

  摘要：

  一个新的（二膦）镍桥双蝶Fe / S簇[[μ-RS ] [μSCS ] Fe 2（CO）6 ] 2 [Ni（二膦）]（1 – 6，R =  p -MeC 6 H 4，Ph，n -Bu;二膦= dppe，dppv，dppb，dppf）是通过新型的含μ-CO阴离子的顺序反应制备的[[μ-RS）（μ-CO ）Fe 2（CO）6 ] -（A型阴离子，由Fe 3（CO）12，RSH和Et 3 N原位产生）带有过量的CS 2，接着处理所得到的μ-CS的2含阴离子[（μ-RS）（μ-S CS）的Fe 2（CO）6 ] - （式乙阴离子）与各种（二膦）的NiCl 2络合物。此外，两种A型阴离子，即[（μ- p -MeC 6 H 4 S）（μ-CO）Fe 2（CO）6 ] -（A 1）和[（μ-PhS）（μ-成功分离出CO）Fe 2（CO）6 ] -（A 2）作为它们的[Et 3 NH]+和[Ph 4 P]

  DOI：

  10.1016/j.jorganchem.2013.06.043
• 作为产物：
  描述：

  十二羰基三铁 、 三乙胺 、 4-甲苯硫酚 以 四氢呋喃 为溶剂， 反应 0.5h， 以62%的产率得到
  参考文献：
  名称：

  （二膦）镍桥双蝶Fe / S团簇配合物的合成及反应性含μ-CO的阴离子Fe / S团簇中间体的分离

  摘要：

  一个新的（二膦）镍桥双蝶Fe / S簇[[μ-RS ] [μSCS ] Fe 2（CO）6 ] 2 [Ni（二膦）]（1 – 6，R =  p -MeC 6 H 4，Ph，n -Bu;二膦= dppe，dppv，dppb，dppf）是通过新型的含μ-CO阴离子的顺序反应制备的[[μ-RS）（μ-CO ）Fe 2（CO）6 ] -（A型阴离子，由Fe 3（CO）12，RSH和Et 3 N原位产生）带有过量的CS 2，接着处理所得到的μ-CS的2含阴离子[（μ-RS）（μ-S CS）的Fe 2（CO）6 ] - （式乙阴离子）与各种（二膦）的NiCl 2络合物。此外，两种A型阴离子，即[（μ- p -MeC 6 H 4 S）（μ-CO）Fe 2（CO）6 ] -（A 1）和[（μ-PhS）（μ-成功分离出CO）Fe 2（CO）6 ] -（A 2）作为它们的[Et 3 NH]+和[Ph 4 P]

  DOI：

  10.1016/j.jorganchem.2013.06.043

文献信息

• Synthetic and Structural Studies on Linear and Macrocyclic Pd- and Pt-Bridged Butterfly Fe/S Cluster Complexes
  作者：Li-Cheng Song、Long-Duo Zhang、Bei-Bei Liu、Shu-Da Ding、Hao Chen、Xiu-Fang Xu、Gui-Lan Fan

  DOI：10.1021/acs.organomet.7b00117

  日期：2017.4.10

  Three types of (diphosphine)Pd- or Pt-bridged butterfly Fe/S cluster complexes have been prepared by a simple and convenient one-pot synthetic method. The first type of such complexes involves the linear (diphosphine)Pd- or Pt-bridged double-butterfly Fe/S clusters [(mu-RS)(mu-S=CS)Fe-2(CO)(6)](2)[M-(diphosphine)] (1-12; M = Pd and Pt; R = Et, t-Bu, Ph, and p-MeC6H4; diphosphine = dppe, dppv, and dppf), which were prepared by sequential reactions of monoanions [(mu-RS)(mu-CO)Fe-2(CO)(6)](-) (formed in situ from Fe-3(CO)(12), RSH, and Et3N) with excess CS2, followed by treatment of the resulting monoanions (mu-RS)(mu-S=CS)Fe-2(CO)(6)](-) with (diphosphine)MCl2. The second type of complexes involves the macrocyclic (diphosphine)M-bridged double-butterfly Fe/S clusters [mu-S(CH2)(4)S-mu][(mu-S=CS)Fe-2(CO)(6)](2)[M(diphosphine)] (13-16; M = Pd and Pt; diphosphine = dppe and dppv), which were prepared by sequential reactions of dianion [mu-S(CH2)(4)S-mu}(mu-CO)Fe-2(CO)(6)}(2)](2-) (generated in situ from Fe-3(CO)(12), dithiol HS(CH2)(4)SH, and Et3N) with excess CS2, followed by treatment of the resultant dianion [mu-S(CH2)(4)S-mu}(mu-S=CS)Fe-2(CO)(6)}(2)](2-) with (diphosphine)MCl2. In contrast, when dithiol HS(CH2)(4)SH was replaced by HS(CH2)(3)SH (a dithiol with a shorter carbon chain), the aforementioned sequential reactions afforded the third type of macrocyclic complexes which involves the (diphosphine)M-bridged quadruple-butterfly Fe/S clusters [mu-S(CH2)(3)S-mu}(mu-S=CS)Fe-2(CO)(6)}(2)](2)[M(diphosphine)](2) (17-20; M = Pd and Pt; diphosphine = dppe and dppv). While the two possible pathways are suggested for production of the two types of novel macrocyclic Fe/S clusters 13-20, respectively, all new complexes 1-20 have been characterized by elemental analysis, spectroscopy, and, for some of them particularly, DFT calculations and X-ray crystallography.