tris(2-aminoethyl)ammonium aluminum ethylenediphosphonatefluoride hydrate | 1202460-14-7

• 英文名称: tris(2-aminoethyl)ammonium aluminum ethylenediphosphonatefluoride hydrate
• CAS: 1202460-14-7
• 化学式: C₄H₈Al₂F₂O₁₂P₄*C₆H₂₂N₄*H₂O
• 分子量: 632.238
• InChiKey: JCYYZNHLKVQWHT-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• sp3杂化的碳原子比例：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  aluminum(III) sulphate octadecahydrate 、 三(2-氨基乙基)胺 、 1,2-乙烯基二膦酸 、 氢氟酸 在 pyridine 作用下， 以 水 为溶剂， 生成 tris(2-aminoethyl)ammonium aluminum ethylenediphosphonatefluoride hydrate
  参考文献：
  名称：

  Formation of helix-containing rods in a hybrid inorganic–organic material

  摘要：

  The novel aluminum ethylenediphosphonate fluoride, [HN(CH2CH2NH3)(3)][Al-2(O3PCH2CH2PO3)(2)F-2] center dot H2O (1) (monoclinic, P2(1)/n, a=12.145(4)angstrom, b=9.265(3)angstrom, c=20.422(6)angstrom, beta=104.952(4)degrees, Z=3, R-1=0.092, wR(2)=0.196) has been synthesized by solvothermal methods in the presence of tris(2-aminoethyl)amine and its structure determined using single microcrystal X-ray diffraction data. Compound 1 is a one-dimensional extended chain structure composed of well-separated anionic [Al-2(O3PCH2CH2PO3)(2)F-2](4-) rods containing helical chains of corner-shared cis-AlO4F2 octahedra at their core. The charge-compensating tris(2-aminoethyl)ammonium cations separate the anionic [Al-2(O3PCH2CH2PO3)(2)F-2](4-) rods that contain either left- OF right-handed helical chains. The incorporation of the organic components into this hybrid material has aided the adoption of one-dimensionality by the compound and defined the pitch of the helical AlO4F chain. (C) 2009 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2009.08.021