| 1386390-55-1

• CAS: 1386390-55-1
• 化学式: C₁₃H₁₀Fe₂N₂O₆S₂
• 分子量: 466.058
• InChiKey: HDFXUVPASAIKRY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  碘甲烷 、 1-[(3,5-二甲基吡唑-1-基)甲基]-3,5-二甲基吡唑 、 十二羰基三铁 、 sulfur 在 n-BuLi 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以20%的产率得到
  参考文献：
  名称：

  Reactivity of Bis(3,5-dimethylpyrazol-1-yl)methyllithium with S or CS₂, Followed by Reaction with Fe₃(CO)₁₂ and Ar₃SnCl or RX: Unexpected Formation of (3,5-Dimethylpyrazol-1-yl)dithioformate Derivatives

  摘要：

  Reaction of bis(3,5-dimethylpyrazol-1-yl)-methyllithium with sulfur at -70 degrees C, followed by reaction with Fe-3(CO)(12) and triaryltin chlorides, yielded trinuclear butterfly cluster complexes. When the triaryltin chlorides were replaced by organic halides, unexpected (3,5-dimethylpyrazol-1-yl)dithioformate derivatives were obtained. In addition, treatment of bis(3,5-dimethylpyrazol-1-yl)methane with n-BuLi at 0 degrees C resulted in partial decomposition to yield a carbene intermediate and a 3,5-dimethylpyrazolate anion. The carbene intermediate readily dimerized, and reaction of the anion with carbon disulfide, and subsequently with Fe-3(CO)(12) and organic halides, also gave the dithioformate derivatives.

  DOI：

  10.1021/om300448a