| 1421745-38-1

• CAS: 1421745-38-1
• 化学式: C₅HMnO₆
• 分子量: 211.997
• InChiKey: SORZJWULGMMGHG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  羰基镁 在 水 作用下， 以 环己烷 为溶剂， 反应 2.0h， 生成 Hydromanganese pentacarbonyl 、
  参考文献：
  名称：

  Stoichiometric H2 production from H2O upon Mn2(CO)10 photolysis

  摘要：

  Photolysis of Mn-2(CO)(10) in an alkane/water biphasic system has resulted in the generation of 1.80 +/- 0.16 mol of hydrogen per mol of Mn-2(CO)(10). Various studies including deuteration have indeed shown water to be the H-2 source while kinetic studies have indicated a strong correlation between the concentration of the key intermediate MnH(CO)(5) with the production rate of H-2. Some of the oxygen atoms of water have been incorporated into a white solid assigned to MnCO3. A mechanism accounting for MnH(CO)(5) formation from Mn-2(CO)(10) photolysis and subsequently H-2 production from MnH(CO)(5) has been proposed. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.10.034